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Merck

731269

2-Phenyl-2-propyl benzodithioate

99% (HPLC)

Synonym(s):

2-Phenylpro-2-yl dithiobenzoate, Benzenecarbodithioic acid 1-methyl-1phenylethyl ester, Cumyl dithiobenzoate

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About This Item

Empirical Formula (Hill Notation):
C16H16S2
CAS Number:
Molecular Weight:
272.43
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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InChI

1S/C16H16S2/c1-16(2,14-11-7-4-8-12-14)18-15(17)13-9-5-3-6-10-13/h3-12H,1-2H3

SMILES string

CC(C)(SC(=S)c1ccccc1)c2ccccc2

InChI key

KOBJYYDWSKDEGY-UHFFFAOYSA-N

assay

99% (HPLC)

form

solid

density

1.125 g/mL at 25 °C

Quality Level

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylates/methacrylamides, and to a lesser extent acrylates/acrylamides and styrenes; Chain Transfer Agent (CTA)

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

219.9 °F

flash_point_c

104.4 °C


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Group 4: Flammable liquids + Type 3 petroleums + Hazardous rank III + Water insoluble liquid

fsl

731269-1G: + 731269-5G: + 731269-VAR: + 731269-BULK:

jan


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Meijie Wang et al.
Journal of biomaterials science. Polymer edition, 31(7), 849-868 (2020-02-06)
In this article, we introduce a pH-responsive charge-reversible and photo-crosslinkable polymer nanoparticle. It is prepared via typical self-assembly from a block copolymer poly((7-(4-vinyl-benzyloxyl)-4-methylcoumarin)-co-acrylicacid)-b-poly((2-dimethylamino) ethyl methacrylate)-co-styrene) (P(VBMC-co-AA)-b-P(DMAEMA-co-St)), whose two blocks have different ionizable moieties. In an aqueous solution of pH ≤
Fatemeh Karimi et al.
Biomaterials, 187, 81-92 (2018-10-12)
Biomaterials are a powerful platform for directing cellular behaviour. Herein, we employed a biomimetic strategy to synthesize a low-fouling polymer functionalized with nano-scale clusters of ligands that bind both integrin and syndecan-4 receptors, as both receptor types are critical in
Assad U Khan et al.
ACS nano, 13(4), 4255-4266 (2019-03-26)
State-of-the-art commercial light-reflecting glass is coated with a metalized film to decrease the transmittance of electromagnetic waves. In addition to the cost of the metalized film, one major limitation of such light-reflecting glass is the lack of spectral selectivity over
Ting Chen et al.
Carbohydrate polymers, 208, 14-21 (2019-01-20)
Modification of cotton fabric to achieve superhydrophobic, self-cleaning and heat resistance is of particular interest for practical applications. Herein, a simple surface modification route is designed to introduce flame retardant component 9, 10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) and low surface energy crosslinked
RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)

Articles

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

See All

Protocols

ウォーリック大学のProf. Dave Haddletonの研究グループによって実証された、ATRPによる重合。

RAFT(可逆的付加-開裂連鎖移動)重合によるPMMAおよびPVAcの典型的な重合手順をご紹介します。

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