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753025

Poly(ethylene glycol) bis[2-(dodecylthiocarbonothioylthio)-2-methylpropionate]

average Mn 10,800

Synonym(s):

PEG BisDDMAT, PEG-RAFT

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About This Item

NACRES:
NA.23
UNSPSC Code:
12352100
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form

solid

Quality Level

100

mol wt

PEG average Mn 10 kDa (n~227), average Mn 10,800

transition temp

Tm 53-60 °C

PDI

≤1.2

storage temp.

2-8°C

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene; acrylate; and acrylamide monomers to make lithographically and biologically important PEG-block copolymers. Chain Transfer Agent (CTA)

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN5588V

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Protocols

ATRPによる重合

ウォーリック大学のProf. Dave Haddletonの研究グループによって実証された、ATRPによる重合。

RAFT剤を用いた典型的な重合反応例

RAFT（可逆的付加-開裂連鎖移動）重合によるPMMAおよびPVAcの典型的な重合手順をご紹介します。

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

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Articles

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

RAFT重合によるタンパク質およびペプチドとポリマーとのコンジュゲート

ペプチドやタンパク質のような生体高分子に合成ポリマーを結合させて修飾することで、特性が強化された極めて高度な新しい種類の生体材料が得られています。

Micro Review：RAFT重合

Micro Review：RAFT（可逆的付加／開裂連鎖移動）重合

Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being