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Merck

A8309

Acethydrazide

90%

Synonym(s):

Acetic acid hydrazide, Acetylhydrazine

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About This Item

Linear Formula:
CH3CONHNH2
CAS Number:
1068-57-1
Molecular Weight:
74.08
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24891331
EC Number:
213-948-7
Beilstein/REAXYS Number:
506165
MDL number:
MFCD00007610
Assay:
90%
Form:
flakes

Key Documents

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InChI

1S/C2H6N2O/c1-2(5)4-3/h3H2,1H3,(H,4,5)

InChI key

OFLXLNCGODUUOT-UHFFFAOYSA-N

SMILES string

CC(=O)NN

assay

90%

form

flakes

impurities

<10% acetic acid

bp

129 °C/18 mmHg (lit.)

Quality Level

200

Related Categories

General description

Acethydrazide is an organic building that undergo catalytic hydrogenation to produce N′-methyl acethydrazide (MAH).

Application

Acethydrazide can be used in the synthesis of (E)-N′-(2-hydroxybenzylidene)acetohydrazide, an ONO pincer ligand.

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Carc. 2 - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

A8309-5KG: + A8309-100G: + A8309-25G: + A8309-BULK: + A8309-VAR: + A8309-5G:

jan

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH8628
STBJ5205
STBG9548
STBG7026
STBG6570

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N E Preece et al.
Journal of chromatography, 573(2), 227-234 (1992-01-17)
Plasma and liver levels of hydrazine were determined at 10, 30, 90 and 270 min in rats given 0.09, 0.27, 0.84 and 2.53 mmol of hydrazine per kg body weight orally by capillary gas chromatography-mass spectrometry of its pentafluorobenzaldehyde adduct
N E Preece et al.
Biochemical pharmacology, 41(9), 1319-1324 (1991-05-01)
15N-NMR has been used to study the metabolism of hydrazine in rats in vivo. Single doses of [15N2]hydrazine (2.0 mmol/kg: 98.6% g atom) were administered to rats and urine collected for 24 hr over ice. A number of metabolites were
D J Fort et al.
Teratogenesis, carcinogenesis, and mutagenesis, 10(6), 463-476 (1990-01-01)
The developmental toxicity of isoniazid (INH) and the metabolites acetylhydrazide (AH) and isonicotinic acid (INA) were examined with the frog embryo teratogenesis assay-Xenopus (FETAX). Late Xenopus laevis blastulae were exposed to INH, AH, and INA for 96 h in two
Shahrzad Tafazoli et al.
Toxicology and applied pharmacology, 229(1), 94-101 (2008-02-26)
Isoniazid is an anti-tuberculosis drug that can cause hepatotoxicity in 20% of patients that is usually associated with an inflammatory response. Hepatocytes when exposed to non-toxic levels of H2O2, to simulate H2O2 formation by inflammatory cells, became twice as sensitive
Mixed valent/geometry, linear, tetranuclear nickel complex bearing ONO pincer ligand exhibiting hitherto unknown ligation mode.
Shalini C, et al.
Polyhedron (2017)
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