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Merck

24-1051

Perchloric acid

suitable for determination of toxic metals, 60.0-62.0%

Synonym(s):

PCA

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About This Item

Linear Formula:
HClO4
CAS Number:
Molecular Weight:
100.46
UNSPSC Code:
12352106
PubChem Substance ID:
MDL number:
Concentration:
60.0-62.0%
Form:
liquid
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form

liquid

reaction suitability

reagent type: oxidant

availability

available only in Japan

concentration

60.0-62.0%

density

1.54 g/cm3

suitability

suitable for determination of toxic metals

SMILES string

OCl(=O)(=O)=O

InChI

1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)

InChI key

VLTRZXGMWDSKGL-UHFFFAOYSA-N



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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Met. Corr. 1 - Ox. Liq. 1 - Skin Corr. 1A - STOT RE 2

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

Group 6: Oxidizing liquids + Perchloric acid + Hazardous rank I

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

24-1051-5-500G-J:4.548173012926E12

jan



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John Greenwood et al.
ACS nano, 9(5), 5520-5535 (2015-04-22)
We shine light on the covalent modification of graphite and graphene substrates using diazonium chemistry under ambient conditions. We report on the nature of the chemical modification of these graphitic substrates, the relation between molecular structure and film morphology, and
Dipanwita Das et al.
Journal of the American Chemical Society, 135(10), 4018-4026 (2013-02-28)
Catalytic four-electron reduction of O2 by ferrocene (Fc) and 1,1'-dimethylferrocene (Me2Fc) occurs efficiently with a dinuclear copper(II) complex [Cu(II)2(XYLO)(OH)](2+) (1), where XYLO is a m-xylene-linked bis[(2-(2-pyridyl)ethyl)amine] dinucleating ligand with copper-bridging phenolate moiety], in the presence of perchloric acid (HClO4) in
Dipanwita Das et al.
Journal of the American Chemical Society, 135(7), 2825-2834 (2013-02-12)
Selective two-electron plus two-proton (2e(-)/2H(+)) reduction of O(2) to hydrogen peroxide by ferrocene (Fc) or 1,1'-dimethylferrocene (Me(2)Fc) in the presence of perchloric acid is catalyzed efficiently by a mononuclear copper(II) complex, [Cu(II)(tepa)](2+) (1; tepa = tris[2-(2-pyridyl)ethyl]amine) in acetone. The E(1/2)