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Merck

163678

Thioacetamide

ACS reagent grade, ≥99.0%, solid

Synonym(s):

TAA, Ethanethioamide

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About This Item

Linear Formula:
CH3CSNH2
CAS Number:
Molecular Weight:
75.13
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
200-541-4
MDL number:
Beilstein/REAXYS Number:
506006
Assay:
≥99.0%
Form:
solid
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Product Name

Thioacetamide, ACS reagent, ≥99.0%

InChI key

YUKQRDCYNOVPGJ-UHFFFAOYSA-N

InChI

1S/C2H5NS/c1-2(3)4/h1H3,(H2,3,4)

SMILES string

CC(N)=S

grade

ACS reagent

assay

≥99.0%

form

solid

Quality Level

solubility

passes test 2%

functional group

amine

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General description

Thioacetamide (TAA) is a thiocarbonyl compound commonly used as a corrosion inhibitor. It prevents corrosion by forming a protective layer on metal surfaces. It undergoes deuterium exchange reaction with D2O to afford N-dideuterated thioacetamide. Infrared spectral investigations of thioacetamide and its deuterated derivative (N-dideuterated thioacetamide) have been reported.

Application

Hepatotoxin and carcinogen. An additive in enantioselective reduction of β-keto esters with immobilized baker′s yeast.
It may also be used as a sulfide source to prepare metal sulfides of metal ions like cadmium, nickel, zinc and copper.
Thioacetamide has been used as a source of sulfur required for the synthesis of CdS nanoparticlesand quantum dots.

signalword

Danger

pictograms

Health hazardExclamation mark

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

163678-6X500G: + 163678-25G: + 163678-100G: + 163678-500G: + 163678-BULK: + 163678-VAR:

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Cancer Research, 17, 954-954 (1952)
Synthesis of copper sulfide nanowhisker via sonochemical way and its characterization
Xu C, et al
Chemistry Letters (Jpn), 32(2), 198-199 (2003)
Synthesis of nickel sulfide powders by thioacetamide in the presence of urea.
Grau J and Akinc M.
Journal of the American Ceramic Society. American Ceramic Society, 80(4), 941-951 (1997)
Effect of molecular structure on the efficiency of amides and thiosemicarbazones used for corrosion inhibition of mild steel in hydrochloric acid
EE Ebenso, et al.
Materials Chemistry and Physics, 60, 79-90 (1999)
Journal of the Chemical Society. Perkin Transactions 1, 659-659 (1992)

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