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221937

Ammonium iodide

greener alternative

ACS reagent, ≥99%

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About This Item

Linear Formula:
NH4I
CAS Number:
12027-06-4
Molecular Weight:
144.94
PubChem Substance ID:
329752286
eCl@ss:
38050607
UNSPSC Code:
12352300
EC Number:
234-717-7
MDL number:
MFCD00011424
Assay:
≥99%
Grade:
ACS reagent
Form:
powder or crystals
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grade

ACS reagent

Quality Level

200

vapor pressure

1 mmHg ( 210.9 °C)

assay

≥99%

form

powder or crystals

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

impurities

≤0.005% insolubles

ign. residue

≤0.05%

pH

4.5-6.5 (25 °C, 50 g/L)

anion traces

Cl- and Br-: ≤0.005%, phosphate (PO43-): ≤0.001%, sulfate (SO42-): ≤0.05%

cation traces

Ba: ≤0.002%, Fe: ≤5 ppm, heavy metals (as Pb): ≤0.001%

greener alternative category

Aligned

SMILES string

N.I

InChI

1S/HI.H3N/h1H;1H3

InChI key

UKFWSNCTAHXBQN-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is used as a ntrogen source for syntheis of many heterocyclic compounds and is also used as a catalyst or redox catalyst in some reactions. Click here for more information.
The high yield and regioselective conversion of an unactivated aziridine to an oxazolidinone using carbon dioxide with ammonium iodide as the catalyst

Application

Catalyst for mild, efficient, and greener dethioacetalization.
Catalyst for mild, efficient, and greener dethioacetalization.

Chemoselective Bromination of Active Methylene and Methyne Compounds by Potassium Bromide, Hydrochloric Acid and Hydrogen Peroxide

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pictograms

Health hazard
GHS08

signalword

Danger

hcodes

H372

Hazard Classifications

STOT RE 1 Oral

target_organs

Thyroid

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

221937-100G:4.548173986708E12 + 221937-500G:4.548173986715E12

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB1803
MKCZ2603
MKCX3347
MKCW1183
0000286363

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Jinho Kim et al.
Organic letters, 14(15), 3924-3927 (2012-07-17)
Copper-mediated regioselective cyanation of indoles and 2-phenylpyridines was developed by using ammonium iodide and DMF as the combined source of a cyano unit under "Pd-free" conditions. Mechanistic studies indicate that the reaction of indoles proceeds through a two-step sequence: electrophilic
Simple and regioselective oxyiodination of aromatic compounds with ammonium iodide and Oxone.
Mohan KVVK, et al.
Tetrahedron Letters, 45(43), 8015-8018 (2004)
Low-Frequency Vibrations in Ammonium Iodide and Ammonium Bromide.
Durig JR and Antion DJ.
J. Chem. Phys. , 51(9), 3639-3647 (1969)
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