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Merck

A9642

Ammonium nitrate

≥99.0%

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About This Item

Linear Formula:
NH4NO3
CAS Number:
Molecular Weight:
80.04
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
229-347-8
MDL number:
Assay:
≥99.0%
Form:
powder or crystals
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Quality Level

assay

≥99.0%

form

powder or crystals

pH

4.5-6.0 (25 °C, 80.40 g/L)

bp

210 °C (lit.)

mp

169 °C (lit.)

SMILES string

N.O[N+]([O-])=O

InChI

1S/HNO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3

InChI key

PRORZGWHZXZQMV-UHFFFAOYSA-N

Application

Ammonium nitrate can be used as a catalyst:
  • For the direct conversion of aryls, heteroaryls, and aliphatic esters to amides.
  • To synthesize 2-aminothiazoles via aerobic oxidative cyclization of ketones with thioureas.
It can also be used to quench Mizoroki-Heckreaction.


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pictograms

Flame over circleExclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 3

Storage Class

5.1C - Ammonium nitrate and ammonium nitrate containing preparations

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Group 1: Oxidizing solids + Nitrates + Hazardous rank I + 1st oxidizing solid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

A9642-50KG: + A9642-6X500G-PW: + A9642-4X2.5KG-PW: + A9642-500G:4548173229089 + A9642-50KG-PW: + A9642-25KG-PW: + A9642-BULK: + A9642-2.5KG:4548173966052 + A9642-25KG: + A9642-VAR:

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Christopher J Harbort et al.
STAR protocols, 1(3), 100226-100226 (2020-12-31)
We present a gnotobiotic system for microbiota reconstitution on Arabidopsis thaliana under contrasting iron availability. This system induces iron starvation in plants by providing an unavailable form, mimicking conditions in alkaline soils. Inoculation of taxonomically diverse bacteria reconstitutes plants with
Deborah Wakeham et al.
Physical chemistry chemical physics : PCCP, 14(15), 5106-5114 (2012-01-31)
The nanostructure of the ethanolammonium nitrate (EtAN)-air surface has been investigated using X-ray reflectometry (XRR), vibrational sum frequency spectroscopy (VSFS) and neutral impact collision ion scattering spectroscopy (NICISS). The XRR data decays more rapidly than expected for a perfectly sharp
Mohammad Mahdi Najafpour et al.
Dalton transactions (Cambridge, England : 2003), 41(34), 10156-10160 (2012-07-27)
Nanoscale manganese oxides within Faujasite zeolite have been synthesized with a simple method and characterized by scanning electron microscopy, X-ray diffraction spectrometry, N(2) adsorption-desorption isotherms, transmission electron microscopy, and atomic absorption spectroscopy. These oxides showed efficient water oxidizing activity in