203548
Lanthanum(III) nitrate hexahydrate
99.999% trace metals basis
Sinónimos:
Nitric acid, lanthanum (III) salt, hexahydrate
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Fórmula lineal:
La(NO3)3 · 6H2O
Número CAS:
Peso molecular:
433.01
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-238-0
MDL number:
Assay:
99.999% trace metals basis
Form:
solid
Servicio técnico
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99.999% trace metals basis
form
solid
reaction suitability
core: lanthanum, reagent type: catalyst
impurities
≤15.0 ppm Trace Rare Earth Analysis
mp
65-68 °C
application(s)
electroplating
material synthesis precursor
SMILES string
[La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI
1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;
InChI key
GJKFIJKSBFYMQK-UHFFFAOYSA-N
General description
Lanthanum(III) nitrate hexahydrate is a transition metal catalyst widely used in many organic transformations such as chemoselective deprotection of acetonides, acetylation of alcohols, phenols, and amines with acetic anhydride, and synthesis of α-amino nitriles. It can also be used as a precursor in the preparation of lanthanum-based nanoparticles.
Application
Lanthanum(III) nitrate hexahydrate can be used as a catalyst in the synthesis of:
- α-aminonitriles by a one-pot three-component coupling of the carbonyl compound, amine, and TMSCN.
- Acetals and geminal diacetates (acylals)from aldehydes.
- Bis(indolyl) methanes under solvent‐free conditions.
Features and Benefits
- Thermal stability
- Low toxicity
- Mild reaction condition
- Chemoselectivity
- Low cost
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2
Clase de almacenamiento
5.1B - Oxidizing hazardous materials
wgk
WGK 2
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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J Tyler Mefford et al.
Physical chemistry chemical physics : PCCP, 21(6), 3327-3338 (2019-01-29)
Perovskite oxides are active room-temperature bifunctional oxygen electrocatalysts in alkaline media, capable of performing the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) with lower combined overpotentials relative to their precious metal counterparts. However, their semiconducting nature necessitates the
Wen-Feng Zhao et al.
Dalton transactions (Cambridge, England : 2003), 41(33), 10091-10096 (2012-08-02)
The reaction between polyoxometalate (POM) [TBA](12)[WZn{Zn(H(2)O)}(2)(ZnW(9)O(34))(2)] (TBA = tetrabutyl ammonium) and lanthanide (Ln) nitrate (Ln = La, Eu and Tb) in a mixed solvent of CH(3)CN and DMF yielded three noncentrosymmetric diamondoid Ln-POM solid materials, {[Ln(2)(DMF)(8)(H(2)O)(6)][ZnW(12)O(40)]}·4DMF (Ln-POM; Ln = La
L P Lopatina et al.
Biofizika, 50(6), 1120-1124 (2005-12-20)
The influence of lanthanoids on exocytosis was investigated. It was shown that gadolinium increases the spontaneous release of the glutamate nonmetabolizing analogue [3H]D-aspartate. It was established using the fluorescent dye acridine orange that gadolinium and lanthanum induce exocytosis. The effect