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Merck

246832

Tri(propylene glycol) diacrylate, mixture of isomers

contains MEHQ and HQ as inhibitors, technical grade

Sinónimos:

TRPGDA

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Fórmula lineal:
H2C=CHCO(OC3H6)3O2CCH=CH2
Número CAS:
Peso molecular:
300.35
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
EC Number:
256-032-2
NACRES:
NA.23
Servicio técnico
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grade

technical grade

Quality Level

vapor density

>1 (vs air)

vapor pressure

<0.01 mmHg ( 20 °C)

form

liquid

contains

150-220 ppm monomethyl ether hydroquinone and hydroquinone (total inhibitor)

refractive index

n20/D 1.45 (lit.)

density

1.03 g/mL at 25 °C (lit.)

SMILES string

CC(COC(C)COC(=O)C=C)OCC(C)OC(=O)C=C

InChI

1S/C15H24O6/c1-6-14(16)20-12(4)9-18-8-11(3)19-10-13(5)21-15(17)7-2/h6-7,11-13H,1-2,8-10H2,3-5H3

InChI key

ZDQNWDNMNKSMHI-UHFFFAOYSA-N

General description

Tri(propylene glycol) diacrylate (TPGDA) is a multifunctional acrylate monomer characterized by its high reactivity and ability to polymerize rapidly under UV or thermal initiation. Its structure includes multiple acrylate groups, which contribute to its crosslinking capability, enhancing the mechanical properties of the resulting polymers. The low viscosity of TPGDA facilitates easy handling and incorporation into formulations.

Application

Tri(propylene glycol) diacrylate, mixture of isomers can be used:
  • As a cross linker to synthesize resins for flexible micromaterials via projection microstereolithography (PμSL) screening formulations to fabricate microfluidic devices for cellular biosensors.
  • As a dopant to prepare pure organic molecules with persistent luminescence at room temperature via intramolecular electronic coupling for forensic fingerprint detection.
  • As a precursor to prepare high mechanical resilience double network hydrogel adhesives for wound healing patches.


pictograms

Exclamation markEnvironment

signalword

Warning

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Clase de almacenamiento

10 - Combustible liquids

wgk

WGK 2

flash_point_f

307.4 °F - closed cup

flash_point_c

153 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Daniel J Duffy et al.
Journal of the American Chemical Society, 124(28), 8290-8296 (2002-07-11)
A model system for the characterization of molecular recognition events in molecularly imprinted polymers (MIPs) is presented. The use of a biologically inspired, three-point hydrogen-bonding motif and a thin film polymeric matrix allows for pre- and post-polymerization binding properties to
R R Tice et al.
Environmental and molecular mutagenesis, 29(3), 240-249 (1997-01-01)
Acrylates may be polymerized to stable surface coatings (paints, lacquers, inks, etc.) by alkylation via the Michaelis-type addition reaction. Thus, acrylates have an inherent potential as electrophiles to be genotoxic, limited in their biological activity by their physicochemical properties. To
L A Nylander-French et al.
In vitro cellular & developmental biology. Animal, 36(9), 611-616 (2001-02-24)
The potential for occupational exposure to the esters of acrylic acid (acrylates) is considerable, and, thus, requires a greater understanding of the their toxicity. Confluent (70-90%) cultures of normal human epidermal keratinocytes (NHEK), dermal fibroblasts (NHDF). or bronchial epithelium (NHBE)