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Merck

356018

Cinc

greener alternative

99.9% trace metals basis, foil, thickness 0.25 mm

Sinónimos:

Zn

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Fórmula lineal:
Zn
Número CAS:
Peso molecular:
65.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
11101719
EC Number:
231-175-3
MDL number:
Servicio técnico
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Nombre del producto

Cinc, foil, thickness 0.25 mm, 99.9% trace metals basis

vapor pressure

1 mmHg ( 487 °C)

Quality Segment

assay

99.9% trace metals basis

form

foil

reaction suitability

core: zinc, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

resistivity

5.8 μΩ-cm, 20°C

thickness

0.25 mm

bp

907 °C (lit.)

mp

420 °C (lit.)

density

7.133 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

[Zn]

InChI

1S/Zn

InChI key

HCHKCACWOHOZIP-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Zinc can be used as a catalyst:
  • For the reduction of nitrobenzenes to aniline derivatives in the presence of ammonium chloride.
  • To synthesize β-hydroxy esters using ketones and α-bromoacetates via Reformatsky reaction.
  • For the transesterification of ethyl acetate and benzyl alcohol to synthesize benzyl acetate in the presence of imidazole.

Preparation Note

  • 50 × 50 mm (approximately 4.5 g)
  • 100 × 100 mm (approximately 18 g)


Clase de almacenamiento

11 - Combustible Solids

wgk

WGK 3

ppe

Eyeshields, Gloves, type N95 (US)



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Shigeki Seto et al.
Bioorganic & medicinal chemistry, 20(3), 1188-1200 (2012-01-21)
The design, synthesis, and evaluation of 6-6-7 tricyclic quinolones containing the strained spirocycle moiety aiming at the GSK-3β inhibitor were described. Among the synthesized compounds, 44, having a cyclobutane ring on a spirocycle, showed excellent GSK-3β inhibitory activity in both
Transesterification reactions catalyzed by a recyclable heterogeneous zinc/imidazole catalyst
Nakatake D, et al.
advanced synthesis and catalysis, 358, 2569-2574 (2016)
Rapid and convenient conversion of nitroarenes to anilines under microwave conditions using nonprecious metals in mildly acidic medium
Keenan C, et al.
Synthetic Communications, 47, 1085-1089 (2017)