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Merck

12322

Iron(III) chloride solution

greener alternative

purum, 45% FeCl3 basis

Sinónimos:

Ferric chloride solution

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About This Item

Fórmula lineal:
FeCl3
Número CAS:
7705-08-0
Peso molecular:
162.20
NACRES:
NA.55
PubChem Substance ID:
329749708
UNSPSC Code:
12352302
MDL number:
MFCD00011005
form:
liquid

Nombre del producto

Iron(III) chloride solution, purum, 45% FeCl3 basis

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Fe](Cl)Cl

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

grade

purum

form

liquid

reaction suitability

reagent type: catalyst
core: iron

greener alternative product characteristics

Catalysis
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sustainability

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concentration

45% (FeCl3)

greener alternative category

, Aligned

Quality Level

100

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Application

Iron(III) chloride may be used for the polymerization of pyrrole and for the preparation of the phenanthrene ring. It is widely employed for the following reactions:
  • polymerizations
  • oxidations
  • oxidative couplings
  • reductions
  • C−C bond formation
  • Ferrier rearrangement
  • one-pot multicomponent condensations
  • Friedel-Crafts reactions
  • cyclization′s
  • glycosidation
  • Prins-type cyclisation

General description

Iron(III) chloride is a mild oxidizing agent. It is widely employed as a Lewis acid in organic synthesis. On crystallization with water, it forms hydrates. It can be prepared by passing chlorine over scrap iron at approximately 650°C.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. The iron catalysts are known to be inexpensive and environmentally benign. Click here for more information.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H290,H314

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1

Clase de almacenamiento

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCW2593
MKCT4382
MKCP5151
MKCM3999
MKCK2729

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Visite la Librería de documentos

Optimum reaction conditions for the polymerization of pyrrole by iron (III) chloride in aqueous solution.
Armes SP.
Synthetic Metals, 20(3), 365-371 (1987)
Recent uses of iron (III) chloride in organic synthesis.
Diaz DD, et al.
Current Organic Chemistry, 10(4), 457-476 (2006)
Eagleson M.
Concise Encyclopedia Chemistry, 553-553 (1994)
Kailiang Wang et al.
The Journal of organic chemistry, 74(2), 935-938 (2008-12-05)
Easily available and nontoxic FeCl(3) catalyzes intramolecular oxidative coupling for the direct construction of the phenanthrene ring using meta-chloroperbenzoic acid as sole oxidant at room temperature in excellent yields. The mechanistic investigations show that FeCl(3)-catalyzed coupling proceeds through the heterolytic
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
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