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Merck

20256

Terc-butilmetil éter

puriss. p.a., ≥99.5% (GC)

Sinónimos:

MTBE, Éter metil terc-butílico

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About This Item

Fórmula lineal:
(CH3)3COCH3
Número CAS:
Peso molecular:
88.15
UNSPSC Code:
12352112
NACRES:
NA.07
PubChem Substance ID:
EC Number:
216-653-1
Beilstein/REAXYS Number:
1730942
MDL number:
assay:
≥99.5% (GC)
technique(s):
GC/GC: suitable
bp:
55-56 °C (lit.)
vapor pressure:
4.05 psi

Nombre del producto

Terc-butilmetil éter, puriss. p.a., ≥99.5% (GC)

InChI key

BZLVMXJERCGZMT-UHFFFAOYSA-N

InChI

1S/C5H12O/c1-5(2,3)6-4/h1-4H3

SMILES string

COC(C)(C)C

vapor density

3.1 (vs air)

vapor pressure

4.05 psi

grade

puriss. p.a.

assay

≥99.5% (GC)

form

liquid

autoignition temp.

705 °F

expl. lim.

15.1 %

technique(s)

GC/GC: suitable

impurities

≤0.0005% peroxides (as H2O2)
≤0.005% free acid (as CH3COOH)
≤0.05% water

evapn. residue

≤0.005%

refractive index

n20/D 1.362-1.376
n20/D 1.369 (lit.)

bp

55-56 °C (lit.)

mp

-110 °C

density

0.736-0.744 g/mL at 20 °C
0.74 g/mL at 25 °C (lit.)

cation traces

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

Quality Level

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Application

tert-Butyl methyl ether is used as a solvent:
  • In the synthesis of acyl azides.
  • In the production of biodiesel.

General description

tert-Butyl methyl ether (TBME) TBME is a common organic solvent used in the Grignard reaction as an alternative to tetrahydrofuran. TBME has been reported to be a butylating agent for active aromatic systems. TBME is also used to facilitate tert-butyl esterification under microwave conditions.

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2

Clase de almacenamiento

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-18.4 °F - closed cup

flash_point_c

-28 °C - closed cup


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J R Hanson et al.
Applied and environmental microbiology, 65(11), 4788-4792 (1999-11-05)
A bacterial strain, PM1, which is able to utilize methyl tert-butyl ether (MTBE) as its sole carbon and energy source, was isolated from a mixed microbial consortium in a compost biofilter capable of degrading MTBE. Initial linear rates of MTBE
Kun-Chang Huang et al.
Chemosphere, 49(4), 413-420 (2002-10-09)
The kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE) in aqueous solutions at various pH, temperature, oxidant concentration and ionic strength levels was studied. The MTBE degradation was found to follow a pseudo-first-order decay model. The pseudo-first-order rate
R J Steffan et al.
Applied and environmental microbiology, 63(11), 4216-4222 (1997-11-15)
Several propane-oxidizing bacteria were tested for their ability to degrade gasoline oxygenates, including methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), and tert-amyl methyl ether (TAME). Both a laboratory strain and natural isolates were able to degrade each compound after
Sarah K Abbott et al.
Lipids, 48(3), 307-318 (2013-01-29)
We have developed a protocol suitable for high-throughput lipidomic analysis of human brain samples. The traditional Folch extraction (using chloroform and glass-glass homogenization) was compared to a high-throughput method combining methyl-tert-butyl ether (MTBE) extraction with mechanical homogenization utilizing ceramic beads.
Ceinwen A Schreiner et al.
Regulatory toxicology and pharmacology : RTP, 70(2 Suppl), S29-S34 (2014-05-24)
Micronucleus and sister chromatid exchange (SCE) tests were performed for vapor condensate of baseline gasoline (BGVC), or gasoline with oxygenates, methyl tert-butyl ether (G/MTBE), ethyl tert butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), t-butyl alcohol (TBA), or

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