201073
Aluminum-tri-sec-butoxide
97%
Synonyme(s) :
Aluminum sec-butoxide
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A propos de cet article
Formule linéaire :
Al[OCH(CH3)C2H5]3
Numéro CAS:
Poids moléculaire :
246.32
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
218-871-2
Beilstein/REAXYS Number:
3910908
MDL number:
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Laissez-nous vous aiderQuality Level
assay
97%
form
liquid
autoignition temp.
763 °F
expl. lim.
9.8 %
reaction suitability
core: aluminum
bp
200-206 °C/30 mmHg (lit.)
density
0.967 g/mL at 25 °C (lit.)
SMILES string
CCC(C)O[Al](OC(C)CC)OC(C)CC
InChI
1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3
InChI key
WOZZOSDBXABUFO-UHFFFAOYSA-N
General description
Aluminum-tri-sec-butoxide is a metal organic chemical vapor deposition precursor and a chelating agent. It is widely used as a sol-gel precursor to deposit alumina thin films by atomic layer deposition method.
Application
Aluminum-tri-sec-butoxide can be used as a precursor :
- To prepare Al2O3-based quasi-solid electrolyte for Li metal anodes. This ensures long cycle lifetime and high constant current density.
- To synthesize nanospinel MgAl2O4 powder by a sol–gel method at low-temperature processing.
- To fabricate transparent superhydrophobic aluminum oxide thin films to prevent soiling of solar panels.
- To synthesize mesoporous alumina with large surface area to fabricate a functional interlayer for separator coating in a Li–S battery. It helps to suppress the shuttle effect and enhances cyclic stability andrateperformance.
Features and Benefits
- Suitable for thin film deposition
- Solubility in various solvents allows for the facile preparation of solution-based precursors
- High thermal stability
- Facilitates the anchoring of catalytic metal nanoparticles onto substrates
Has been utilized in making high-surface-area alumina using 2,4-pentanedione (Aldrich product P775-4) as a chelating agent.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3
Classe de stockage
3 - Flammable liquids
wgk
WGK 3
flash_point_f
78.8 °F - closed cup
flash_point_c
26 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Clark, H.W. et al.
Microporous Mater., 6, 115-115 (1996)
Polykarpos A Lazaridis et al.
Frontiers in chemistry, 6, 295-295 (2018-08-04)
The valorization of lignin that derives as by product in various biomass conversion processes has become a major research and technological objective. The potential of the production of valuable mono-aromatics (BTX and others) and (alkyl)phenols by catalytic fast pyrolysis of
Chem. Abstr., 124, 328279f-328279f (1996)