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Merck

278513

Gadolinium(III) oxide

powder, 99.9% trace metals basis

Synonyme(s) :

Digadolinium trioxide, Gadolinia, Gadolinium oxide, Gadolinium trioxide

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A propos de cet article

Formule linéaire :
Gd2O3
Numéro CAS:
Poids moléculaire :
362.50
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352303
EC Number:
235-060-9
MDL number:
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assay

99.9% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: gadolinium

mp

2330 °C (lit.)

density

7.407 g/mL at 20 °C (lit.)

SMILES string

O=[Gd]O[Gd]=O

InChI

1S/2Gd.3O

InChI key

RNYFGGMJZRTZKO-UHFFFAOYSA-N

General description

Gadolinium(III) oxide is a rare-earth oxide known for its high thermal stability and unique magnetic properties, making it valuable in various high-temperature applications. It is widely used as a host material in solid-state lasers, where doping with rare-earth ions like neodymium or erbium enhances laser efficiency and enables specific wavelengths for telecommunications and medical procedures3. Additionally, its nanoparticles are utilized in biomedical imaging as MRI contrast agents due to their excellent biocompatibility and ability to improve image resolution.

Application

Gadolinium(III) oxide is used as a dopant in zirconia to improve the ionic conductivity of solid electrolytes in solid oxide fuel cells. Its presence enhances the performance and efficiency of these energy conversion devices. It is also used as a component in thermal barrier coatings for gas turbine engines and other high-temperature applications. Its thermal stability and low thermal conductivity make it suitable for protecting components from extreme heat.


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Hazard Classifications

Eye Irrit. 2

Classe de stockage

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Andrée-Anne Guay-Bégin et al.
Langmuir : the ACS journal of surfaces and colloids, 28(1), 774-782 (2011-10-06)
The performance of nanomaterials for biomedical applications is highly dependent on the nature and the quality of surface coatings. In particular, the development of functionalized nanoparticles for magnetic resonance imaging (MRI) requires the grafting of hydrophilic, nonimmunogenic, and biocompatible polymers
Nikesh Gupta et al.
International journal of nanomedicine, 7, 5491-5500 (2012-12-13)
Mesoporous silica nanoparticles coencapsulating gadolinium oxide and horseradish peroxidase (HRP) have been synthesized in the aqueous core of sodium bis-(2-ethylhexyl) sulfosuccinate (AOT)-hexane-water reverse micelle. The average diameter of these silica particles is around 25 nm and the particles are spherical
Zijian Zhou et al.
Advanced materials (Deerfield Beach, Fla.), 24(46), 6223-6228 (2012-09-14)
Monodisperse Gd(2) O(3) -embedded iron oxide (GdIO) nanoparticles can simultaneously enhance the local magnetic field intensities of each other under an external magnetic field and result in synergistic enhancement of T(1) and T(2) effects. GdIO nanoparticles have the unique property