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Merck

518018

Lithium iodide

greener alternative

99.9% trace metals basis

Synonyme(s) :

Lithium(1+)iodide

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A propos de cet article

Formule linéaire :
LiI
Numéro CAS:
Poids moléculaire :
133.85
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-822-5
MDL number:
Assay:
99.9% trace metals basis
Form:
powder
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assay

99.9% trace metals basis

form

powder

reaction suitability

core: lithium

greener alternative product characteristics

Design for Energy Efficiency
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sustainability

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impurities

≤1500.0 ppm Trace Metal Analysis

mp

446 °C (lit.)

density

3.49 g/mL at 25 °C (lit.)

application(s)

battery precursors
catalysts
material synthesis precursor

greener alternative category

SMILES string

[Li+].[I-]

InChI

1S/HI.Li/h1H;/q;+1/p-1

InChI key

HSZCZNFXUDYRKD-UHFFFAOYSA-M

General description

Lithium iodide is widely used as an electrolyte additivein dye-sensitized solar cells and Li-S batteries, as it enables long cyclelife. It is also used as a phosphor for neutron detection.
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Application

Lithium iodide(LiI)can be used as an electrolyte additive:

  • To prepare biodegradable polymer electrolytes.Rice starch complexed with LiI shows enhanced ionic conductivity as theaddition of LiI increases the number of mobile charge carriers.
  • For Li-S batteries. LiIforms a protective coating on the surface of both negative and positiveelectrodes and prevents the dissolution of polysulfides on the cathode sidewhich significantly enhances cell rate performance.
It can also be used to prepare Li-basedscintillators with enhanced thermal neutron detection efficiency.

Features and Benefits

  • 10 mesh particle size provides a larger surface area for better reactivity and interaction in chemical processes, improving efficiency in energy storage and conversion.
  • 99.9% trace metals purity facilities better charge/ion transport leading to improved performances.
  • Enhances durability and Longevity of energy & electronic devices due to minimum metal impurities.
  • Low metal impurities reduce structural defects in solar cells and contribute to the formation of a stable electrolyte in batteries.


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11 - Combustible Solids

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Feixiang Wu et al.
Advanced materials (Deerfield Beach, Fla.), 27(1), 101-108 (2014-11-05)
Lithium Iodide (LiI) is reported as a promising electrolyte additive for lithium-sulfur batteries. It induces formation of Li-ion-permeable protective coatings on both positive and negative electrodes, which prevent the dissolution of polysulfides on the cathode and reduction of polysulfides on
Seon-Joo Choi et al.
ACS applied materials & interfaces, 10(37), 31404-31412 (2018-08-28)
All-solid-state lithium batteries (ASSLBs) based on sulfide solid electrolytes (SEs) have received great attention because of the high ionic conductivity of the SEs, intrinsic thermal safety, and higher energy density achievable with a Li metal anode. However, studies on practical
Yu-il Kang et al.
ChemSusChem, 8(22), 3799-3804 (2015-10-17)
Dye-sensitized solar cells (DSCs) with long-term stability are produced using polymer-gel electrolytes (PGEs). In this study, we introduce the formation of PGEs using in situ gelation with poly(methyl methacrylate) (PMMA) particles and graphene fillers that are pre-deposited on the counter electrodes.