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Merck

21198

Calcium ionophore IV

Selectophore, function tested

Synonyme(s) :

N,N-Dicyclohexyl-N′,N′-dioctadecyl-3-oxapentanediamide, N,N-Dicyclohexyl-N′,N′-dioctadecyl-diglycolic diamide, ETH 5234

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A propos de cet article

Formule empirique (notation de Hill) :
C52H100N2O3
Numéro CAS:
Poids moléculaire :
801.36
NACRES:
NB.61
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
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description

for ion-selective electrodes

Quality Level

product line

Selectophore

quality

function tested

mp

50-53 °C

SMILES string

CCCCCCCCCCCCCCCCCCN(CCCCCCCCCCCCCCCCCC)C(=O)COCC(=O)N(C1CCCCC1)C2CCCCC2

InChI

1S/C52H100N2O3/c1-3-5-7-9-11-13-15-17-19-21-23-25-27-29-31-39-45-53(46-40-32-30-28-26-24-22-20-18-16-14-12-10-8-6-4-2)51(55)47-57-48-52(56)54(49-41-35-33-36-42-49)50-43-37-34-38-44-50/h49-50H,3-48H2,1-2H3

InChI key

CLLKVTAGSOWKHA-UHFFFAOYSA-N

General description

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Application

Selected application examples
Calcium ionophore IV (ETH 5234) was used in preparing membrane for the pseudoreference electrode in tetrahydrofuran, in a study to demonstrate electrochemical sample matrix elimination for trace level potentiometric detection.
Calcium ionophore IV may be used in the preparation of Ca2+-selective membrane utilizing AlGaN/GaN transistors for potentiometric calcium ion detection.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Extremely lipophilic Ca2+-selective ionophore for chemical sensors of long lifetime; it induces selectivities for Ca over Mg, Na and K of 104, 106, and 108, respectively.

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany


Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Contenu apparenté


Karin Y Chumbimuni-Torres et al.
Analytical chemistry, 80(15), 6114-6118 (2008-06-24)
Potentiometric sensors are today sufficiently well understood and optimized to reach ultratrace level (subnanomolar) detection limits for numerous ions. In many cases of practical relevance, however, a high electrolyte background hampers the attainable detection limits. A particularly difficult sample matrix
Mohsen Asadnia et al.
Analytica chimica acta, 987, 105-110 (2017-09-17)
We demonstrate highly selective and sensitive potentiometric ion sensors for calcium ion detection, operated without the use of a reference electrode. The sensors consist of AlGaN/GaN heterostructure-based transistor devices with chemical functionalisation of the gate area using poly (vinylchloride)-based (PVC)
Lowering the Detection Limit of Solvent Polymeric Ion-Selective Membrane Electrodes. 2. Influence of Composition of Sample and Internal Electrolyte Solution
Sokalski, T.; et al.
Analytical Chemistry, 71(6), 1210-1214 (1999)