311448
Sodium periodate
ACS reagent, ≥99.8%
Synonyme(s) :
Sodium (meta)periodate
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A propos de cet article
Formule linéaire :
NaIO4
Numéro CAS:
Poids moléculaire :
213.89
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-197-6
MDL number:
Assay:
≥99.8%, 99.8-100.3% dry basis (ACS specification)
Grade:
ACS reagent
Form:
crystalline powder
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ACS reagent
Quality Level
assay
≥99.8%, 99.8-100.3% dry basis (ACS specification)
form
crystalline powder
reaction suitability
reagent type: oxidant
impurities
≤0.02% other halogens (as Cl)
pH
3.5-5.5 (25 °C, 107 g/L)
mp
300 °C (dec.) (lit.)
cation traces
Mn: ≤3 ppm
storage temp.
room temp
SMILES string
[Na+].[O-]I(=O)(=O)=O
InChI
1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI key
JQWHASGSAFIOCM-UHFFFAOYSA-M
General description
Sodium periodate is an inorganic salt commonly used as an oxidizing agent for various organic substrates and a co-oxidant in a few other oxidation reactions. The oxidation of sodium periodate takes place in a water medium, but an organic co-solvent is used for organic substrates that are insoluble in water.
Application
Sodium periodate can be used as an oxidizing agent:
- In the selective oxidation of sulfides to sulfoxides.
- For the oxidative cleavage of a variety of 1,2-diols to generate aldehydes or ketones.
- In the oxidation of diaryl, dialkyl, and aryl alkyl selenides to the respective selenoxides.
- In the selective alkene epoxidation and alkane hydroxylation reactions.
- In the selective oxidation of activated cellulose to obtain dialdehyde cellulose (DAC) by cleavage of the bond between C2 – C3 in the glucose unit.
- It can also be used as an iodinating agent for the iodination of arenes and halo compounds.
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1
target_organs
Thyroid
Classe de stockage
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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