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516813

Peroxyde d′hydrogène solution

greener alternative

50 wt. % in H2O, stabilized

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A propos de cet article

Formule empirique (notation de Hill) :
H2O2
Numéro CAS:
7722-84-1
Poids moléculaire :
34.01
UNSPSC Code:
12352304
NACRES:
NA.21
PubChem Substance ID:
329757730
EC Number:
231-765-0
Beilstein/REAXYS Number:
3587191
MDL number:
MFCD00011333
Assay:
48-52% H2O2 basis (by KMnO4, titration)
Concentration:
50 wt. % in H2O
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agency

suitable for EPA 200.7

Quality Level

100

vapor pressure

23.3 mmHg ( 30 °C)

assay

48-52% H2O2 basis (by KMnO4, titration)

reaction suitability

reaction type: C-H Activation, reagent type: catalyst, reagent type: oxidant

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

50 wt. % in H2O

mp

−40 °C

solubility

water: soluble at 20 °C

density

1.197 g/mL at 20 °C

greener alternative category

Aligned

storage temp.

2-8°C

SMILES string

OO

InChI

1S/H2O2/c1-2/h1-2H

InChI key

MHAJPDPJQMAIIY-UHFFFAOYSA-N

General description

The product is a 50% solution of hydrogen peroxide in water. Hydrogen peroxide is more commonly being used as a green oxidizing agent. It is a better alternative to other oxidants because it has high active oxygen content and the by-product is water.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

Hydrogen peroxide solution may be used as an oxidizing agent in the following reactions:
  • Epoxidation of alkenes in the presence of homogeneous metal catalyst.
  • Oxidative halogenation in the presence of metal catalyst.
  • Oxidation of sulfides to sulfoxides and sulfones in the presence of polymer immobilised catalyst.

Other Notes

Contains proprietary inorganic tin-based stabilizer

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Ox. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Classe de stockage

5.1B - Oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificats d'analyse (COA)

Lot/Batch Number
MKCZ6386
MKCX9749
MKCX5293
SDBB1595
STBL4164

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Consulter la Bibliothèque de documents

Oxidative halogenation with ?green? oxidants: oxygen and hydrogen peroxide.
Podgorsek A, et al.
Angewandte Chemie (International Edition in English), 48(45), 8424-8450 (2009)
Efficient and selective hydrogen peroxide-mediated oxidation of sulfides in batch and segmented and continuous flow using a peroxometalate-based polymer immobilised ionic liquid phase catalyst.
Doherty S, et al.
Green Chemistry, 17(3), 1559-1571 (2015)
Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant.
Grigoropoulou G, et al.
Green Chemistry, 5(1), 1-7 (2003)
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