10452
Ruthenium(III) chloride trihydrate
technical grade, solid
Synonym(s):
Ruthenium trichloride trihydrate
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About This Item
Linear Formula:
RuCl3 · 3H2O
CAS Number:
Molecular Weight:
261.47
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Ruthenium(III) chloride trihydrate, technical
SMILES string
O.O.O.Cl[Ru](Cl)Cl
InChI
1S/3ClH.3H2O.Ru/h3*1H;3*1H2;/q;;;;;;+3/p-3
InChI key
ZTWIEIFKPFJRLV-UHFFFAOYSA-K
grade
technical
form
solid
reaction suitability
core: ruthenium
reaction type: C-H Activation
reagent type: catalyst
Quality Level
Application
Ruthenium(III) chloride trihydrate can be used as a catalyst:
- Precursor for the hydroamidation of terminalalkynes.
- For the hydrolysis of 4-nitrobenzonitrile to 4-nitrobenzamide in the presence of 1,3,5-triaza-7-phosphaadamantane.
- For the oxidation of thioethers to sulfones in the presence of sodium periodate and acetonitrile.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Zhiwei Jiang et al.
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Tenaglia, A.; Terranova, E. et al.
Tetrahedron Letters, 32, 1169-1169 (1991)
Sasaki, Y.; Dixneuf, P. H.
The Journal of Organic Chemistry, 52, 314-314 (1987)
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Silva D, et al.
Synlett, 28, 815-818 (2017)
Ceria supported ruthenium(0) nanoparticles: Highly efficient catalysts in oxygen evolution reaction.
Elif Demir et al.
Journal of colloid and interface science, 534, 704-710 (2018-10-01)
Ruthenium(0) nanoparticles were successfully prepared on the surface of ceria (Ru0/CeO2) and used as catalysts on glassy carbon electrode (GCE) in oxygen evolution reaction (OER) from water electrolysis at room temperature. Ru0/CeO2 on GCE exhibits high catalytic activity for OER
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