208272
Vanadium(III) chloride
97%
Synonym(s):
Vanadium trichloride
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About This Item
Linear Formula:
VCl3
CAS Number:
Molecular Weight:
157.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-744-6
MDL number:
Assay:
97%
Form:
powder
Quality Level
assay
97%
form
powder
reaction suitability
core: vanadium, reagent type: catalyst
density
3 g/mL at 25 °C (lit.)
SMILES string
Cl[V](Cl)Cl
InChI
1S/3ClH.V/h3*1H;/q;;;+3/p-3
InChI key
HQYCOEXWFMFWLR-UHFFFAOYSA-K
General description
Vanadium(III) chloride is a crystalline solid with variable oxidation states. It is widely used as a catalyst in organic synthesis, polymerization processes, and redox batteries. It acts as a reducing agent.
Application
Vanadium chloride may be used as a reduction agent to determine nitrates and nitrites in water samples.It may be used in redox flow batteries. Vanadium trichloride catalyses Pinacol coupling reactions of benzaldehyde in water. it also acts as a mild and efficient catalyst for the chemoselective deprotection of acetonides.
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Thanh-Binh Nguyen et al.
Environmental management, 63(4), 455-465 (2018-02-06)
The objective of this study was to examine the feasibility of sewage sludge composting using a simple aeration method. Two consecutive composting trials (run A and run B) using Japanese sludge and woodchips (1:1, v/v) were conducted in cubic boxes
Xiaoliang Xu et al.
The Journal of organic chemistry, 70(21), 8594-8596 (2005-10-08)
A catalytic pinacol coupling using water as a solvent was performed by a catalytic amount of vanadium(III) chloride and metallic Al as a co-reductant. A combination forms a binary catalytic system, being in sharp contrast to the reaction in organic
Heyam Mohamed Ali Sidahmed et al.
BMC complementary and alternative medicine, 13, 183-183 (2013-07-23)
Mitrella kentii (M. kentii) (Bl.) Miq, is a tree-climbing liana that belongs to the family Annonaceae. The plant is rich with isoquinoline alkaloids, terpenylated dihydrochalcones and benzoic acids and has been reported to possess anti-inflammatory activity. The purpose of this