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Merck

208272

Vanadium(III) chloride

97%

Synonym(s):

Vanadium trichloride

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About This Item

Linear Formula:
VCl3
CAS Number:
Molecular Weight:
157.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-744-6
MDL number:
assay:
97%
form:
powder

Product Name

Vanadium(III) chloride, 97%

InChI key

HQYCOEXWFMFWLR-UHFFFAOYSA-K

InChI

1S/3ClH.V/h3*1H;/q;;;+3/p-3

SMILES string

Cl[V](Cl)Cl

assay

97%

form

powder

reaction suitability

core: vanadium
reagent type: catalyst

density

3 g/mL at 25 °C (lit.)

Quality Level

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Application

Vanadium chloride may be used as a reduction agent to determine nitrates and nitrites in water samples.It may be used in redox flow batteries. Vanadium trichloride catalyses Pinacol coupling reactions of benzaldehyde in water. it also acts as a mild and efficient catalyst for the chemoselective deprotection of acetonides.

General description

Vanadium(III) chloride is a crystalline solid with variable oxidation states. It is widely used as a catalyst in organic synthesis, polymerization processes, and redox batteries. It acts as a reducing agent.

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Heyam Mohamed Ali Sidahmed et al.
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A M Dolgorukova et al.
Bulletin of experimental biology and medicine, 165(5), 635-639 (2018-09-19)
The study of NO metabolism in chicken embryos showed that the intensity of oxidation of both endogenous and exogenous for the embryo NO donors to nitrate is determined by the presence or state of NO targets, rather than donor concentration.
Lingjun Kong et al.
Small (Weinheim an der Bergstrasse, Germany), 14(21), e1800639-e1800639 (2018-04-20)
Hierarchical porous structures are highly desired for various applications. However, it is still challenging to obtain such materials with tunable architectures. Here, this paper reports hierarchical nanomaterials with oriented 2D pores by taking advantages of thermally instable bonds in vanadium-based
Mustafa Ahmed Abdel-Reheim et al.
Pharmaceutical biology, 55(1), 1972-1983 (2017-07-22)
Saponins from different sources are historically reported in Chinese medicine to possess many beneficial effects. However, insufficient experimental data are available regarding the hepatoprotective potential of Quillaja bark saponin. The protective effect of Quillaja saponaria Molina (Quillajaceae) bark triterpenoid saponin
Novel vanadium chloride/polyhalide redox flow battery.
Skyllas-Kazacos M
Journal of Power Sources, 124(1), 299-302 (2003)

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