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Merck

381071

2-Aminoterephthalic acid

99%

Synonym(s):

2-Aminobenzene-1,4-dicarboxylic acid

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About This Item

Linear Formula:
H2NC6H3-1,4-(CO2H)2
CAS Number:
Molecular Weight:
181.15
UNSPSC Code:
12352106
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2805625
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Product Name

2-Aminoterephthalic acid, 99%

InChI

1S/C8H7NO4/c9-6-3-4(7(10)11)1-2-5(6)8(12)13/h1-3H,9H2,(H,10,11)(H,12,13)

SMILES string

Nc1cc(ccc1C(O)=O)C(O)=O

InChI key

GPNNOCMCNFXRAO-UHFFFAOYSA-N

assay

99%

form

powder, crystals or chunks

reaction suitability

reaction type: solution phase peptide synthesis

mp

324 °C (dec.) (lit.)

application(s)

peptide synthesis

Quality Level

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Application

2-Aminoterephthalic acid can be used to synthesize:
  • Lanthanide coordination polymers with 1,10-phenanthroline by hydrothermal method.
  • Blue-emitting derivatives of 2-aminoterephthalic acid.
  • Amino-functionalized Zr-terephthalate (UiO-66), an excellent catalyst for selective synthesis of jasminaldehyde.
  • IRMOF-3, a zinc aminoterephthalate metal-organic framework useful as a catalyst for the Knoevenagel condensation of benzaldehyde and ethyl cyanoacetate.
  • Polymeric composite membrane with excellent CO2 separation capabilities.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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An amino-modified Zr-terephthalate metal?organic framework as an acid?base catalyst for cross-aldol condensation
Vermoortele F, et al.
Chemical Communications (Cambridge, England), 47(5), 1521-1523 (2011)
Weiwei Zhao et al.
PloS one, 12(6), e0178513-e0178513 (2017-06-06)
UiO-66 analogues are good candidates as stationary phase in HPLC because of their chemical/thermal stability, large surface area, and two cage structures. Here, two UiO-66 analogues, UiO-66-NH2 and UiO-67, were synthesized and used as stationary phase in HPLC to evaluate
Hao Zhang et al.
Nanomaterials (Basel, Switzerland), 10(9) (2020-09-17)
A combination of calcination and hydrothermal processing was used to prepare a g-C3N4/UiO-66-NH2/CdS photocatalyst, and the degradation of tetracycline (TC) over this material was assessed. The photocatalytic performance of this nanocomposite was approximately 4.4 and 2.3 times those of CdS
Kristian Blindheim Lausund et al.
Dalton transactions (Cambridge, England : 2003), 46(48), 16983-16992 (2017-11-28)
Thin films of metal-organic frameworks (MOFs) prepared using all-gas-phase techniques such as atomic/molecular layer deposition (ALD/MLD) are emerging due to their potential for enabling suitable applications. Their high and specific porosity enables their use as membranes for separations and as
Farhad Ahmadijokani et al.
Dalton transactions (Cambridge, England : 2003), 48(36), 13555-13566 (2019-07-30)
Mixed-matrix membranes (MMMs) are promising candidates for carbon dioxide separation. However, their application is limited due to improper dispersion of fillers within the polymer matrix, poor interaction of fillers with polymer chains, and formation of defects and micro-voids at the

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