429120
3-Methoxybenzyl bromide
98%
Synonym(s):
1-Bromomethyl-3-methoxybenzene
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Linear Formula:
CH3OC6H4CH2Br
CAS Number:
Molecular Weight:
201.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
Form:
liquid
Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.575 (lit.)
bp
152 °C (lit.)
density
1.436 g/mL at 25 °C (lit.)
functional group
bromo
SMILES string
COc1cccc(CBr)c1
InChI
1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3
InChI key
ZKSOJQDNSNJIQW-UHFFFAOYSA-N
General description
3-Methoxybenzyl bromide is a benzyl bromide derivative.
Application
3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives.
It may be used in the synthesis of the following:
It may be used in the synthesis of the following:
- 6-(3-methoxyphenyl)-hexane-2,4-dione
- N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine
- 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate
- 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Application of sulfur ylide mediated epoxidations in the asymmetric synthesis of ?-hydroxy-d-lactones. Synthesis of a mevinic acid analogue and (+)-prelactone B.
Aggarwal VK, et al.
Tetrahedron Asymmetry, 60(43), 9725-9733 (2004)
Synthesis of (-)-kainic acid using chiral lithium amides in an asymmetric dearomatizing cyclization.
Clayden J, et al.
Tetrahedron, 58(23), 4727-4733 (2002)
Yang Zhang et al.
The Journal of organic chemistry, 71(12), 4516-4520 (2006-06-06)
A mild protocol for the conversion of beta-ketoesters and beta-diketones to carboxylic acids with use of CAN in CH3CN is described. The method is compatible with a number of functional groups, and can generate carboxylic acids under neutral conditions at