448303
16-Mercaptohexadecanoic acid
90%
Synonym(s):
MHDA
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About This Item
Linear Formula:
HS(CH2)15CO2H
CAS Number:
Molecular Weight:
288.49
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Product Name
16-Mercaptohexadecanoic acid, 90%
InChI
1S/C16H32O2S/c17-16(18)14-12-10-8-6-4-2-1-3-5-7-9-11-13-15-19/h19H,1-15H2,(H,17,18)
SMILES string
OC(=O)CCCCCCCCCCCCCCCS
InChI key
INOAASCWQMFJQA-UHFFFAOYSA-N
assay
90%
form
solid
mp
65-69 °C
Quality Level
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Application
MHA forms SAMs on gold dipyramids which can be used in the fabrication of nanoresonators for shell-isolated nanoparticle enhanced raman spectroscopy (SHINERS). It can also be used to surface modify gold electrodes that can be used for sensitive detection of clozapine. Gold surfaces can be self-assembled with MHA by polymer pen lithography (PPL) which can be potentially used in bioengineering.
General description
16-Mercaptohexadecanoic acid (MHA) is a long chained alkanethiol which forms self-assembled monolayers (SAMs) on a variety of surfaces.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
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Landon J Brower et al.
Beilstein journal of nanotechnology, 8, 2307-2314 (2017-11-29)
Integration of surface-anchored metal-organic frameworks (surMOFs) within hierarchical architectures is necessary for potential sensing, electronic, optical, or separation applications. It is important to understand the fundamentals of film formation for these surMOFs in order to develop strategies for their incorporation
Sensitive detection of clozapine using a gold electrode modified with 16-mercaptohexadecanoic acid self-assembled monolayer.
Huang Fei, et al.
Talanta, 72(2), 457-462 (2007)
Modification of surfaces of silver nanoparticles for controlled deposition of silicon, manganese, and titanium dioxides.
Abdulrahman HB, et al.
Applied Surface Science, 427, 334-339 (2018)
Large-area molecular patterning with polymer pen lithography.
Eichelsdoerfer DJ, et al.
Nature Protocols, 8(12), 2548-2548 (2013)
Brandon H Bowser et al.
Nanomaterials (Basel, Switzerland), 8(9) (2018-08-26)
Metal-organic frameworks (MOFs) are extremely porous, crystalline materials with high surface area for potential use in gas storage, sequestration, and separations. Toward incorporation into structures for these applications, this study compares three variations of surface-bound and free-standing HKUST-1 MOF structures:
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