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Merck

463922

Ammonium metatungstate hydrate

99.99% trace metals basis

Synonym(s):

Ammonium tungsten oxide hydrate, Hexaammonium wolframate hydrate

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About This Item

Linear Formula:
(NH4)6H2W12O40 · xH2O
CAS Number:
12333-11-8
Molecular Weight:
2956.30 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
24870120
UNSPSC Code:
12352302
EC Number:
234-733-4
MDL number:
MFCD00150662
Assay:
99.99% trace metals basis
Form:
powder

Key Documents

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Product Name

Ammonium metatungstate hydrate, 99.99% trace metals basis

InChI key

ZBHPUDGBNLMJQH-UHFFFAOYSA-F

InChI

1S/6H3N.9H2O.32O.12W/h6*1H3;9*1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;6*+1;+2/p-8

SMILES string

N.N.N.N.N.N.O.O[W]1O[W](O)(=O)(O1)O[W]2(=O)(=O)O[W](O)(=O)(O2)O[W]3(=O)(=O)O[W](O)(=O)(O3)O[W]4(=O)(=O)O[W](O)(=O)(O[W]5(=O)(=O)O[W](O)(=O)(O[W]6(=O)(=O)O[W](O)(O)O6)O5)O4

assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst

impurities

≤150.0 ppm Trace Metal Analysis

mp

100 °C (dec.) (lit.)

Quality Level

100

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Application

Ammonium metatungstate can be used as a precursor to synthesize:
  • Carbon-supported tungsten catalyst for hydrogenolysis of cellulose.
  • Reduced tungsten and mixed tungsten oxide catalysts for bifunctional hydroisomerization of n-alkanes.
  • Hybrid 2D/3D tungsten diselenide transistors via chemical vapor deposition method.

General description

Ammonium metatungstate is a Keggin-type heteropoly compound. It can be prepared by polycondensation of ammonium tungstate solutions. It is widely used as a precursor for preparing tungsten catalysts for hydrocracking and as a fuel cell catalyst.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H302,H318

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ5476
0000482892
0000482892
0000480501
0000480501

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Gwang Hwi An et al.
Small (Weinheim an der Bergstrasse, Germany), 16(43), e2003326-e2003326 (2020-10-01)
While a hexagonal WS2 monolayer, grown by chemical vapor deposition, exhibits distinctive patterns in photoluminescence mapping, segmented with alternating S-vacancy (SV) and W-vacancy (WV) domains in a single crystal, the formation mechanism for native alternating defect domains remains unresolved to
Jung Ho Kim et al.
Scientific reports, 9(1), 9164-9164 (2019-06-27)
Nanophotonic devices manipulating light for high-speed computing are a counterpart of speed-limited electronic circuits. Although plasmonic circuits are a promising platform for subwavelength miniaturization, the logic-operation principle is still limited to mimicking those of photonic waveguides using phase shifts, polarization
Hanyu Zhang et al.
Nanoscale, 12(15), 8344-8354 (2020-04-03)
By understanding how the environmental composition impacts the optoelectronic properties of transition metal dichalcogenide monolayers, we demonstrate that simple photoluminescence (PL) measurements of tungsten disulfide (WS2) monolayers can differentiate relative humidity environments. In this paper, we examine the PL and
Xiao Zhang et al.
Science advances, 6(40) (2020-10-02)
The direct growth of single-walled carbon nanotubes (SWCNTs) with narrow chiral distribution remains elusive despite substantial benefits in properties and applications. Nanoparticle catalysts are vital for SWCNT and more generally nanomaterial synthesis, but understanding their effect is limited. Solid catalysts
Ze-Da Meng et al.
Nanoscale research letters, 6(1), 459-459 (2011-07-22)
WO3-treated fullerene/TiO2 composites (WO3-fullerene/TiO2) were prepared using a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy, and UV-vis analysis. A methyl orange (MO) solution
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