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Merck

510033

Raney®-Nickel

W.R. Grace and Co. Raney® 2400, slurry, in H2O, active catalyst

Synonym(s):

Raney Ni, Nickel sponge

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About This Item

Linear Formula:
AlNi
CAS Number:
7440-02-0
NACRES:
NA.22
PubChem Substance ID:
24873469
UNSPSC Code:
12161600
MDL number:
MFCD00167392

Key Documents

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InChI

1S/Al.Ni

SMILES string

[Al].[Ni]

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

form

slurry

reaction suitability

core: nickel, reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 2400

concentration

in H2O

Quality Level

100

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Application

Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

signalword

Danger

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS0191
MKCS5529
MKCN4832
MKCJ4866
MKCF1215

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A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the
Marilia O S Seijo et al.
Journal of dental education, 77(5), 648-655 (2013-05-10)
Including students' perceptions in the educational process is considered a key component in monitoring the quality of academic programs. This study aimed to evaluate the concept of one's learning experience in endodontic teaching from the perspective of a group of
Palatally anchored maxillary molar mesialization using the mesialslider.
Benedict Wilmes et al.
Journal of clinical orthodontics : JCO, 47(3), 172-179 (2013-05-11)
Fariborz Amini et al.
International journal of orthodontics (Milwaukee, Wis.), 24(1), 43-44 (2013-06-05)
In this report, we present an uncomplicated approach to overcome lingual rolling of mandibular molars during orthodontic treatment, by using rectangular NiTi arch wire in twist fashion through the molar tube. The sequential steps of the twist manoeuvre on a
Picture of the month. Allergic contact dermatitis to nickel-containing dental work.
Emma F Johnson et al.
JAMA pediatrics, 167(6), 581-582 (2013-06-05)
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Articles

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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