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Merck

510068

Raney®-Nickel

W.R. Grace and Co. Raney® 3202, slurry, in H2O, active catalyst

Synonym(s):

Nickel sponge

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About This Item

Linear Formula:
AlNi
CAS Number:
7440-02-0
NACRES:
NA.22
PubChem Substance ID:
24873472
UNSPSC Code:
12161600
MDL number:
MFCD00167392

Key Documents

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InChI

1S/Al.Ni

SMILES string

[Al].[Ni]

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

form

slurry

reaction suitability

core: nickel, reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 3202

concentration

in H2O

Quality Level

100

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Related Categories

Application

Useful as a selective reducing agent for hydrogenation of organic compounds

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

signalword

Danger

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBP2086V
MKBD1888V
MKBD1888
MKBC2716
MKBB5212

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Barrero, A. F.; Alvarez-Manzaneda, E. J. et al.
Synthesis, 197-197 (2000)
Nitrile reduction in the presence of Boc-protected amino groups by catalytic hydrogenation over palladium-activated Raney-nickel.
B Klenke et al.
The Journal of organic chemistry, 66(7), 2480-2483 (2001-04-03)
Tsukinoki, T.; Kanda, T.
Tetrahedron Letters, 41, 5865-5865 (2000)
Toth, M.; Somsak, L.,
Tetrahedron Letters, 42, 2723-2723 (2001)
Michał Sarul et al.
Advances in clinical and experimental medicine : official organ Wroclaw Medical University, 22(2), 253-260 (2013-05-28)
Cognizance of the mechanical properties of nickel-titanium archwires is necessary for the management of orthodontic therapy with fixed appliances. Acting on the periodontium with forces that are too heavy may lead to such complications as: pain, tooth root resorption and
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Articles

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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