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Merck

550787

Vanadyl acetylacetonate

98%

Synonym(s):

VO(acac)2, Vanadium(IV)-oxy acetylacetonate

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About This Item

Linear Formula:
OV(C5H7O2)2
CAS Number:
3153-26-2
Molecular Weight:
265.16
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
24879146
EC Number:
221-590-8
Beilstein/REAXYS Number:
4138236
MDL number:
MFCD00000032

Product Name

Vanadyl acetylacetonate, 98%

InChI key

JFHJZWAQYMGNBE-SUKNRPLKSA-L

InChI

1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/q;;;+2/p-2/b2*4-3-;;

SMILES string

CC(=O)\C=C(\C)O[V](=O)O\C(C)=C/C(C)=O

assay

98%

form

solid

mp

235 °C (dec.) (lit.)

Quality Level

100

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Application

Vanadyl acetylacetonate may be used as a precursor for the preparation of vanadium dioxide thin films for applications in “intelligent” window coating and data storage.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000516835
0000516835
MKCZ9328
MKCZ9325
0000460989

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Doped and un-doped vanadium dioxide thin films prepared by atmospheric pressure chemical vapour deposition from vanadyl acetylacetonate and tungsten hexachloride: the effects of thickness and crystallographic orientation on thermochromic properties.
Binions R,et al.
Journal of Materials Chemistry, 17, 4652-4660 (2007)
Jack S Shamie et al.
ChemSusChem, 10(3), 533-540 (2016-11-20)
In this study, a new mechanism for the reduction of vanadyl acetylacetonate, VO(acac)
Szymon Kowalski et al.
International journal of molecular sciences, 20(2) (2019-01-13)
Pancreatic cancer is characterized by one of the lowest five-year survival rates. In search for new treatments, some studies explored several metal complexes as potential anticancer drugs. Therefore, we investigated three newly synthesized oxidovanadium(IV) complexes with 2-methylnitrilotriacetate (bcma3-), N-(2-carbamoylethyl)iminodiacetate (ceida3-)
On the effects of electric fields in aerosol assisted chemical vapour deposition reactions of vanadyl acetylacetonate solutions in ethanol
Warwick MEA and Binions R
Journal of Nanoscience and Nanotechnology, 11(9), 8126-8131 (2011)
Tengfei Li et al.
Nature communications, 8(1), 390-390 (2017-09-01)
There is a global effort to convert sunlight into fuels by photoelectrochemically splitting water to form hydrogen fuels, but the dioxygen byproduct bears little economic value. This raises the important question of whether higher value commodities can be produced instead
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