Sodium azide

Name: Sodium azide
Brand: ALDRICH

purum p.a., ≥99.0% (T)

Synonym(s):

Hydrazoic acid sodium salt, NSC 3072

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About This Item

Linear Formula:

NaN₃

CAS Number:

26628-22-8

Molecular Weight:

65.01

NACRES:

NA.21

PubChem Substance ID:

57652281

UNSPSC Code:

12352201

EC Number:

247-852-1

MDL number:

MFCD00003536

assay:

≥99.0% (T)

form:

crystals

solubility:

H₂O: 0.1 g/mL, clear, colorless

Product Name

Sodium azide, purum p.a., ≥99.0% (T)

InChI key

PXIPVTKHYLBLMZ-UHFFFAOYSA-N

InChI

1S/N3.Na/c1-3-2;/q-1;+1

SMILES string

[Na]N=[N+]=[N-]

grade

purum p.a.

assay

≥99.0% (T)

form

crystals

solubility

H₂O: 0.1 g/mL, clear, colorless

anion traces

chloride (Cl^-): ≤50 mg/kg
sulfate (SO₄^2-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

Quality Level

200

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Related Categories

Azides

Chemistry & Biochemicals

Lab Chemicals

Salts

Application

Catalyst for:

Oxidative decarboxylation
Michael addition reactions

Reagent for synthesis of

Blue fluorescent copolymers
Metal phosphonates
Arenes via aminations

Involved in regioselective synthesis of prianosin B

Other Notes

Schmidt reaction with aldehydes and carboxylic acids, a review

pictograms

GHS06,GHS08,GHS09

signalword

Danger

hcodes

H300 + H310 + H330,H373,H410

pcodes

P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral

target_organs

Brain

supp_hazards

EUH032

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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G.I. Koldobski et al.

Russ. Chem. Rev., 47, 1084-1084 (1978)

Three-, two-, and one-dimensional metal phosphonates based on [hydroxy(4-pyridyl)methyl]phosphonate: M{(4-C5H4N)CH(OH)PO3}(H2O) (M = Ni, Cd) and Gd{(4-C5H4N)CH(OH)P(OH)O2}3.6H2O.

Deng-Ke Cao et al.

Inorganic chemistry, 44(10), 3599-3604 (2005-05-10)

Based on the [hydroxy(4-pyridyl)methyl]phosphonate ligand, three compounds with formula Ni{(4-C(5)H(4)N)CH(OH)PO(3)}(H(2)O) (1), Cd{(4-C(5)H(4)N)CH(OH)PO(3)}(H(2)O) (2), and Gd{(4-C(5)H(4)N)CH(OH)P(OH)O(2)}(3).6H(2)O (3) have been synthesized under hydrothermal conditions. The crystal data for 1 are as follows: orthorhombic, space group Pbca, a = 8.7980(13) A, b =

V. N. Telvekar and K. A. Sasane,

Synlett, 18, 2778-2780 (2010)

H. Chen, et al.,

Macromolecules, 43, 3613-3623 (2010)

Y. Wada, et al.,

Tetrahedron, 65, 1059-1062 (2009)

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