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Merck

83440

Activated Nickel Catalyst

Synonym(s):

Nickel sponge

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About This Item

CAS Number:
7440-02-0
UNSPSC Code:
12141729
PubChem Substance ID:
329769077
MDL number:
MFCD00011137

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InChI

1S/Ni

SMILES string

[Ni]

InChI key

PXHVJJICTQNCMI-UHFFFAOYSA-N

description

Application Test Activity ((Nitrobenzene hydrogenation) >= 22 ml/min*g)

assay

90-95% Ni basis (content, ICP)

form

suspension (water)

shelf life

limited shelf life, expiry date on the label

reaction suitability

core: nickel

Quality Level

100

Application

Catalyst for homocoupling of halobenzenes; benzyl halide coupling; synthesis of β-hydroxynitriles; xylylene cycloadditions; synthesis of 3-arylpropanenitriles.

signalword

Danger

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCBS4336V
BCBR3287V
BCBQ4094V
BCBP7490V
BCBP2348V

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Inaba, S.; Rieke, R. D.
Synthesis, 842-842 (1984)
Inaba, S.; Matsumoto, H.; Rieke, R. D.
The Journal of Organic Chemistry, 49, 2093-2093 (1984)
Inaba, S.;Wehmeyer, R. M. et al.
The Journal of Organic Chemistry, 53, 339-339 (1988)
Inaba, S.; Rieke, R. D.
Tetrahedron Letters, 26, 155-155 (1985)
Inaba, S.; Rieke, R. D.
Tetrahedron Letters, 24, 2451-2451 (1983)
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