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Merck

02574

1,1-Dichloroethylene

analytical standard

Synonym(s):

Vinylidene chloride

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About This Item

Linear Formula:
CH2=CCl2
CAS Number:
75-35-4
Molecular Weight:
96.94
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329747460
EC Number:
200-864-0
Beilstein/REAXYS Number:
1733365
MDL number:
MFCD00011653

Product Name

1,1-Dichloroethylene, analytical standard

InChI key

LGXVIGDEPROXKC-UHFFFAOYSA-N

InChI

1S/C2H2Cl2/c1-2(3)4/h1H2

SMILES string

ClC(Cl)=C

grade

analytical standard

vapor density

3.46 (vs air)

vapor pressure

9.68 psi ( 20 °C)

assay

≥99.9% (GC)

autoignition temp.

968 °F

shelf life

limited shelf life, expiry date on the label

contains

~0.02% 4-methoxyphenol as stabilizer

expl. lim.

15.5 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.424-1.426

bp

30-32 °C (lit.)

mp

−122 °C (lit.)

density

1.213 g/mL at 20 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-8°C

Quality Level

100

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Application

1,1-Dichloroethylene has been used as a reference standard for the analysis of residual 1,1-dichloroethylene in pharmaceutical drug substances by headspace gas chromatography (HS-GC). It may be used as a reference standard for the determination of the analyte in urban and industrial air, whole blood and water by GC coupled with mass spectrometry (MS).

General description

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food. Find all available reference materials for compounds listed in 10/2011 here


1,1-Dichloroethylenes are a group of volatile organic compounds (VOCs), which are characterized by high vapor pressure and low water solubility.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 1 - STOT RE 1 Inhalation - STOT RE 2 Oral

target_organs

Liver, Nose

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-9.4 °F - closed cup

flash_point_c

-23.0 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN8521
BCCL1488
BCCM4090
BCCJ6471
BCCG7232

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Determination of volatile organic compounds in urban and industrial air from Tarragona by thermal desorption and gas chromatography-mass spectrometry
Ras-Mallorqui MR, et al.
Talanta, 72(3), 941-950 (2007)
Michiya Kawaguchi et al.
Developmental dynamics : an official publication of the American Association of Anatomists, 236(11), 2973-2979 (2007-10-20)
Mesothelia comprise the epithelial covering of coelomic organs and line the cavities in which they are housed. Mesothelia contribute to the vasculature of the heart and the intestinal tract by developmental processes of epithelial-mesenchymal transition (EMT), migration, and differentiation into
Quantification of 31 volatile organic compounds in whole blood using solid-phase microextraction and gas chromatography-mass spectrometry
Blount BC, et al.
Journal of Chromatography. B, Biomedical Applications, 832(2), 292-301 (2006)
J Sochman et al.
Physiological research, 63(2), 157-165 (2014-01-09)
The concept of vena contracta space reduction in tricuspid valve position was tested in an animal model. Feasibility of specific artificial obturator body (REMOT) fixed to the right ventricular apex and interacting with tricuspid valve leaflets was evaluated in three
Determination of volatile organic compounds in water by headspace solid-phase microextraction gas chromatography coupled to tandem mass spectrometry with triple quadrupole analyzer
Cervera MI, et al.
Analytica Chimica Acta, 704(1-2), 87-97 (2011)
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