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Merck

09935

Ammonium pyrrolidinedithiocarbamate

≥98.0% (NT), powder with lumps, puriss. p.a.

Synonym(s):

1-Pyrrolidinecarbodithioic acid ammonium salt, APDC, Ammonium pyrrolidinecarbodithioate, PDC, PDTC

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About This Item

Linear Formula:
C5H9NS2 · NH3
CAS Number:
Molecular Weight:
164.29
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
225-834-4
MDL number:
Beilstein/REAXYS Number:
3730472
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Product Name

Ammonium pyrrolidinedithiocarbamate, purum p.a., ≥98.0% (NT)

InChI key

MDDIUTVUBYEEEM-UHFFFAOYSA-N

InChI

1S/C5H9NS2.H3N/c7-5(8)6-3-1-2-4-6;/h1-4H2,(H,7,8);1H3

SMILES string

N.SC(=S)N1CCCC1

grade

purum p.a.

assay

≥98.0% (NT)

form

(powder or powder with lumps)

mp

153-155 °C (lit.)

cation traces

Bi: ≤10 mg/kg, Ca: ≤10 mg/kg, Cd: ≤10 mg/kg, Co: ≤10 mg/kg, Cr: ≤10 mg/kg, Cu: ≤10 mg/kg, Fe: ≤10 mg/kg, K: ≤50 mg/kg, Mg: ≤10 mg/kg, Mn: ≤10 mg/kg, Na: ≤50 mg/kg, Ni: ≤10 mg/kg, Pb: ≤10 mg/kg, Zn: ≤10 mg/kg

Quality Level

Gene Information

human ... RELA(5970)

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Application

for the precipitation of As, Bi, Cd, Co, Cu, Fe, Mn, Ni, Pb, Sb, Sn, V, Zn from acidic solutions

Other Notes

Reagent used for the extraction and pre-concentration of heavy metals with an organic solvent from aqueous solutions for atomic absorption spectroscopy, AAS. MIBK (methyl isobutyl ketone) is the solvent of choice; The extract can be directly injected into the flame

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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B. Welz
Atomabsorptionsspektrometrie (1983)
Determination of arsenic (III), arsenic (V), antimony (III), antimony (V), selenium (IV) and selenium (VI) by extraction with ammonium pyrrolidinedithiocarbamate-methyl isobutyl ketone and electrothermal atomic absorption spectrometry.
Subramanian KS and Meranger JC.
Analytica Chimica Acta, 124(1), 131-142 (1981)
J.D. Kinrade et al.
Analytical Chemistry, 46, 1894-1894 (1974)
M.S. Cresser
Solvent Extraction in Flame Spectroscopic Analysis (1978)
Ammonium pyrrolidinedithiocarbamate-modified activated carbon micro-column extraction for the determination of As (III) in water by graphite furnace atomic absorption spectrometry.
Jiang Y, et al.
Microchimica Acta, 161(1-2), 137-1421 (2008)

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