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Merck

426466

Methylamine solution

40 wt. % in H₂O, solution

Synonym(s):

Monomethylamine

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About This Item

Linear Formula:
CH3NH2
CAS Number:
74-89-5
Molecular Weight:
31.06
NACRES:
NA.21
PubChem Substance ID:
24866706
UNSPSC Code:
12352100
MDL number:
MFCD00008104
Beilstein/REAXYS Number:
741851
bp:
48 °C
vapor pressure:
280 mmHg ( 20 °C)
659 mmHg ( 40 °C)

Product Name

Methylamine solution, 40 wt. % in H2O

InChI

1S/CH5N/c1-2/h2H2,1H3

SMILES string

CN

InChI key

BAVYZALUXZFZLV-UHFFFAOYSA-N

vapor density

1.07 (vs air)

vapor pressure

280 mmHg ( 20 °C)
659 mmHg ( 40 °C)

autoignition temp.

806 °F

concentration

40 wt. % in H2O

refractive index

n20/D 1.37

bp

48 °C

density

0.897 g/mL at 25 °C

functional group

amine

Quality Level

200

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Application

Methylamine solution may be used as a LC-MS/MS mobile phase in the perchlorate analysis of milk and yogurt samples.
It may be used in the synthesis of the following:
  • 9-fluorenylmethyl N-methylcarbamate and tert-butyl N-methylcarbamate
  • 7-methylamino-2-(2-quinolyl)tropone
  • 2,5-meso-pyrrolidines
  • 2-(4-chlorophenyl)-N-methylacetamide
  • 1,3-benzoxazine derivatives from eugenol

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

14.0 °F - closed cup

flash_point_c

-10 °C - closed cup

ppe

Faceshields, Gloves, Goggles

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB6998
MKCZ6367
MKCZ0121
SDBB3743
MKCX6618

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Dohyung Kim et al.
Nature communications, 10(1), 444-444 (2019-01-27)
Organic-inorganic metal halide perovskites have gained considerable attention for next-generation photovoltaic cells due to rapid improvement in power conversion efficiencies. However, fundamental understanding of underlying mechanisms related to light- and bias-induced effects at the nanoscale is still required. Here, structural
Preparation of Tetrahydroisoquinoline-3-ones Via Cyclization of Phenyl Acetamides Using Eaton's Reagent.
Yang Q, et al.
Organic Syntheses, 44-54 (2012)
Zacharias Amara et al.
Organic & biomolecular chemistry, 10(35), 7148-7157 (2012-07-27)
Novel 2,5-meso-pyrrolidines have been straightforwardly synthesized from readily available symmetrical double Michael acceptors. The key step rested on an aza-Michael addition of primary alkylamines to bis-enones. Competitive Rauhut-Currier and aza-Michael reactions have been highlighted in protic solvent. Ultrasound activation associated
Orthogonally Protected N-Methyl-Substituted α-Aminoglycines.
Jiang G, et al.
Protein and peptide letters, 3(4), 219-224 (1996)
Han Chen et al.
Nature, 550(7674), 92-95 (2017-09-05)
Recent advances in the use of organic-inorganic hybrid perovskites for optoelectronics have been rapid, with reported power conversion efficiencies of up to 22 per cent for perovskite solar cells. Improvements in stability have also enabled testing over a timescale of
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