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Merck

221260

Ammonium iron(III) sulfate dodecahydrate

ACS reagent, 99%

Synonym(s):

Ammonium ferric sulfate dodecahydrate

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About This Item

Linear Formula:
NH4Fe(SO4)2 · 12H2O
CAS Number:
Molecular Weight:
482.19
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-382-4
MDL number:
assay:
98.5-102.0% (ACS specification)
99%
grade:
ACS reagent
form:
crystals

Product Name

Ammonium iron(III) sulfate dodecahydrate, ACS reagent, 99%

InChI key

LCPUDZUWZDSKMX-UHFFFAOYSA-K

InChI

1S/Fe.H3N.2H2O4S.12H2O/c;;2*1-5(2,3)4;;;;;;;;;;;;/h;1H3;2*(H2,1,2,3,4);12*1H2/q+3;;;;;;;;;;;;;;;/p-3

SMILES string

N.O.O.O.O.O.O.O.O.O.O.O.O.[Fe+3].OS([O-])(=O)=O.[O-]S([O-])(=O)=O

grade

ACS reagent

assay

98.5-102.0% (ACS specification)
99%

form

crystals

reaction suitability

reagent type: catalyst
core: iron

impurities

≤0.01% insolubles
≤0.05% not NH4OH pptd.

pH

1 (25 °C, 482.2 g/L)

mp

39-41 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
nitrate (NO3-): ≤0.01%

cation traces

Cu: ≤0.003%
Fe2+:, passes test (limit about 0.001%)
Zn: ≤0.003%

storage temp.

2-8°C

Quality Level

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Application

Ammonium ferric sulfate dodecahydrate may be used as a catalyst to synthesize:
  • Isoamyl acetate from acetic acid and isoamyl alcohol.
  • 2-Amino-5-(5-nitro-2-thienyl)-1,3,4-thiadiazole from 5-nitrothiophene-2-carboxaldehyde thiosemicarbazone via oxidative cyclization.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Antituberculosis agents VIII: Synthesis and in vitro antimycobacterial activity of alkyl a-[5-(5-nitro-2-thienyl)-1, 3, 4-thiadiazole-2-ylthio] acetates.
Foroumadi A, et al.
Il Farmaco (Societa Chimica Italiana : 1989), 58(11), 1073-1076 (2003)
Study on the Catalytic Synthesis of Isoamyl Acetate Catalyzed by Ammonlum Ferric Sulface Dodecahydrate
Ying Z, et al.
Contemporary Chemical Industry (2006)
Tomasz Kleszczewski et al.
Journal of pharmaceutical and biomedical analysis, 29(4), 755-759 (2002-07-03)
A method for spectrophotometric determination of L-ascorbic acid (vitamin C) in tissues by flow injection analysis is reported. The procedure is based on the oxidation of analyse with iron(III) and 2,2'-dipyridyl. Concentrations of vitamin C in the range of 0.5-20
Contemporary Chemical Industry null
Mossbauer-Effect Study of the Ferroelectric Transitions in Potassium Ferrocyanide Trihydrate and Ferric Ammonium Sulfate Dodecahydrate.
Gleason TG and Walker JC.
Physical Review, 188(2), 893-893 (1969)

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