283134
Hexamethyldisilathiane
synthesis grade
동의어(들):
(TMS)2S, HMDS, Bis(trimethylsilyl) sulfide, NSC 252160
조직 및 계약 가격을 보려면 로그인를 클릭합니다.
크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
(CH3)3SiSSi(CH3)3
CAS 번호:
Molecular Weight:
178.44
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
222-201-4
Beilstein/REAXYS Number:
1698358
MDL number:
InChI key
RLECCBFNWDXKPK-UHFFFAOYSA-N
InChI
1S/C6H18SSi2/c1-8(2,3)7-9(4,5)6/h1-6H3
SMILES string
C[Si](C)(C)S[Si](C)(C)C
form
liquid
quality
synthesis grade
refractive index
n20/D 1.4586 (lit.)
bp
164 °C (lit.)
density
0.846 g/mL at 25 °C (lit.)
Quality Level
Application
Hexamethyldisilathiane may be used in the bis-O-demethylation of dimethoxy aromatic compounds.
It may also be used as a sulfur source in the following conversion:
It may also be used as a sulfur source in the following conversion:
- Amides and lactams to their corresponding sulfur analogs.
- Allyl alcohols to diallyl sulfides.
- Transition metal halides to metal sulfides.
- Aryl iodides to diaryl sulfides.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 3
저장 등급
3 - Flammable liquids
wgk
WGK 3
flash_point_f
73.4 °F - closed cup
flash_point_c
23 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Conversion of amides and lactams to thioamides and thiolactams using hexamethyldisilathiane.
Smith DC
The Journal of Organic Chemistry, 59(2), 348-354 (1994)
Counterattack reagents sodium trimethylsilanethiolate and hexamethyldisilathiane in the bis-O-demethylation of aryl methyl ethers.
Hwu JR
The Journal of Organic Chemistry, 55(24), 5987-5991 (1990)
Direct synthesis of diallyl sulfides from allyl alcohols and hexamethyldisilathiane.
Tsay SC
Tetrahedron, 49(40), 8969-8976 (1993)
The use of hexamethyldisilathiane for the synthesis of transition metal sulfides.
Carmalt CJ
Polyhedron, 22(9), 1255-1262 (2003)
Copper-Catalyzed Production of Diaryl Sulfides Using Aryl Iodides and a Disilathiane.
Ogiwara Y
Synlett (2017)
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
고객지원팀으로 연락바랍니다.