462063
(R)-(+)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde
95%
동의어(들):
(+)-N-Boc-N,O-isopropylidene-D-serinal, tert-Butyl (R)-(+)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate
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제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C11H19NO4
CAS 번호:
Molecular Weight:
229.27
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3651554
Assay:
95%
Quality Level
assay
95%
optical activity
[α]23/D +90°, c = 1 in chloroform
impurities
<6% methyl (R)-(+)-3-(tert-butoxycarbonyl)-2,2-dimethyl-4-oxazolidinecarboxylate (CAS 95715-87-0)
refractive index
n20/D 1.445 (lit.)
bp
67 °C/0.3 mmHg (lit.)
density
1.06 g/mL at 25 °C (lit.)
functional group
aldehyde, ether
SMILES string
[H]C(=O)[C@H]1COC(C)(C)N1C(=O)OC(C)(C)C
InChI
1S/C11H19NO4/c1-10(2,3)16-9(14)12-8(6-13)7-15-11(12,4)5/h6,8H,7H2,1-5H3/t8-/m0/s1
InChI key
PNJXYVJNOCLJLJ-QMMMGPOBSA-N
Application
Employed in the synthesis of fluorinated analogs of glutemic and glutamine.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
저장 등급
10 - Combustible liquids
wgk
WGK 3
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
R Dave et al.
Amino acids, 24(3), 245-261 (2003-04-23)
Gamma-fluorinated analogues of glutamic acid and glutamine are compounds of biological interest. Syntheses of such compounds are extensively reviewed in this article. 4-fluoroglutamic acid was prepared as a mixture of racemic diastereomers by Michael reaction, inverse-Michael reaction or by electrophilic