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Merck

544094

Bis(trifluoromethane)sulfonimide lithium salt

99.95% trace metals basis

동의어(들):

Bis(trifluoromethylsulfonyl)amine lithium salt, Lithium bistrifluoromethanesulfonimidate

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
CF3SO2NLiSO2CF3
CAS 번호:
Molecular Weight:
287.09
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
EC Number:
415-300-0
Beilstein/REAXYS Number:
6625414
MDL number:
Assay:
99.95% trace metals basis
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Quality Level

assay

99.95% trace metals basis

mp

234-238 °C (lit.)

functional group

fluoro

SMILES string

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key

QSZMZKBZAYQGRS-UHFFFAOYSA-N

General description

Bis(trifluoromethane)sulfonimide lithium salt is a synthetic reagent.

LiTFSI exhibits high ionic conductivity and electrochemical stability. Used as an electrolyte additive in energy storage devices.

Application

Bis(trifluoromethane)sulfonimide lithium salt may be used in the following studies:
  • As ionic liquid in the preparation of gel polymer electrolytes (GPEs) using solution casting technique.
  • To compose unique nonflammable electrolyte, having thermal stability beyond 200°C and a remarkably high transference number, for lithium-ion batteries.
  • As electrolyte for the Li-O2 batteries.
  • To compose the solid polymer electrolytes for lithium batteries.


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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

target_organs

Nervous system

저장 등급

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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문서 라이브러리 방문


문서

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.


Nurul Nadiah Sa'adun et al.
TheScientificWorldJournal, 2014, 254215-254215 (2014-11-29)
Gel polymer electrolytes (GPEs) are developed using poly(1-vinylpyrrolidone-co-vinyl acetate) [P(VP-co-VAc)] as the host polymer, lithium bis(trifluoromethane) sulfonimide [LiTFSI] as the lithium salt and ionic liquid, and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide [EMImTFSI] by using solution casting technique. The effect of ionic liquid
Dominica H C Wong et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(9), 3327-3331 (2014-02-12)
The flammability of conventional alkyl carbonate electrolytes hinders the integration of large-scale lithium-ion batteries in transportation and grid storage applications. In this study, we have prepared a unique nonflammable electrolyte composed of low molecular weight perfluoropolyethers and bis(trifluoromethane)sulfonimide lithium salt.
Efficiency improvement using bis (trifluoromethane) sulfonamide lithium salt as a chemical additive in porphyrin based organic solar cells
Arrechea S, et al.
Nanoscale, 8(41), 17953-17962 (2016)