651664
Tetrabutylammonium azide
동의어(들):
N,N,N-Tributyl-1-butanaminium azide, Tetrabutylammonium nitride
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제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C16H36N4
CAS 번호:
Molecular Weight:
284.48
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Form:
solid
form
solid
Quality Level
reaction suitability
core: ammonium, reaction type: click chemistry
mp
84-88 °C (lit.)
functional group
amine, azide
storage temp.
2-8°C
SMILES string
[N-]=[N+]=[N-].CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/C16H36N.N3/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-3-2/h5-16H2,1-4H3;/q+1;-1
InChI key
GMRIOAVKKGNMMV-UHFFFAOYSA-N
Application
Reagent for synthesis of:
Reagent for:
Catalyst for syslic carbonate formation
- Heteroarylannulated bicyclic morpholines
- Cyanimide-based inhibitors of cathepsin C
- Trimethylene carbonate
Reagent for:
- Aerobic oxidative transformation of primary azides to nitriles
- Substitution reactions at tetracoordinate boron
Catalyst for syslic carbonate formation
Tetrabutylammonium azide can be used as a reagent for the synthesis of:
It is also used as a catalyst for cyclic carbonate formation.
- Heteroarylannulated bicyclic morpholines
- Cyanimide-based inhibitors of cathepsin C
- Trimethylene carbonate
- Aerobic oxidative transformation of primary azides to nitriles
- Substitution reactions at tetracoordinate boron
It is also used as a catalyst for cyclic carbonate formation.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
저장 등급
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Aerobic oxidative transformation of primary azides to nitriles by ruthenium hydroxide catalyst.
He J, et al.
The Journal of Organic Chemistry, 76(11), 4606-4610 (2011)
Synthesis of bicyclic sugar azido acids and their incorporation in cyclic peptides.
Peri F, et al.
Chemical Communications (Cambridge, England), 2303-2304 (2000)
A facile catalytic synthesis of trimethylene carbonate from trimethylene oxide and carbon dioxide.
Darensbourg DJ, et al.
Green Chemistry, 12(8), 1376-1379 (2010)