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Merck

701122

Iron(III) chloride

greener alternative

≥99.9% trace metals basis

동의어(들):

Ferric chloride, Iron trichloride, Molysite

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
FeCl3
CAS 번호:
Molecular Weight:
162.20
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-729-4
MDL number:
Assay:
≥99.9% trace metals basis
Form:
powder or crystals
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vapor density

5.61 (vs air)

vapor pressure

1 mmHg ( 194 °C)

assay

≥99.9% trace metals basis

form

powder or crystals

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

technique(s)

cell culture | mammalian: suitable

impurities

≤1000.0 ppm Trace Metal Analysis

mp

304 °C (lit.)

greener alternative category

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

General description

Iron(III) chloride is brownish to black crystalline solid that is highly soluble in water. As a moderately strong Lewis acid, FeCl3 can form complex compounds and adducts with Lewis bases, making it a useful catalyst in various chemical reactions.
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Application

Iron(III) chloride can be used:
  • As a precursor to prepare Fe(III)-chlorophyll complex. Fe(III) enhances the performance of chlorophyll as a dye sensitizer in DSSCs by forming complex compounds with metal-ligand charge transfer properties, leading to increased efficiency and improved paramagnetic properties.
  • As a catalyst /modifying agent to prepare high performance porous carbon for lithium-ion battery anodes. The addition of FeCl3 enhances the graphitization of porous carbon without significantly affecting the layer spacing and also the specific surface area and pore volume of porous carbon.
  • As a co-catalyst to fabricate liquid catalyzed fuel cell (LCFC) for direct conversion from carbohydrates to electricity. It helps to improve the hydrolysis of carbohydrate and enhances the electron transfer from carbohydrates to anode.

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

저장 등급

13 - Non Combustible Solids



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문서

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Prof. Randal Lee discusses iron oxide magnetic nanospheres and nanocubes design considerations for biosensing applications.

리튬 이온 배터리는 휴대성, 재충전 가능성, 저렴한 비용 등의 특성으로 인해 전력 저장 장치로 널리 사용됩니다.


Recent uses of iron (III) chloride in organic synthesis.
Diaz DD, et al.
Current Organic Chemistry, 10(4), 457-476 (2006)
Photoredox chemistry of iron (III) chloride and iron (III) perchlorate in aqueous media. A comparative study.
David F and David PG.
The Journal of Physical Chemistry, 80(6), 579-583 (1976)
Optimum reaction conditions for the polymerization of pyrrole by iron (III) chloride in aqueous solution.
Armes SP.
Synthetic Metals, 20(3), 365-371 (1987)