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크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
[CH3(CH2)3]4NCl
CAS 번호:
Molecular Weight:
277.92
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352107
EC Number:
214-195-7
MDL number:
Beilstein/REAXYS Number:
3571227
제품 이름
Tetrabutylammonium chloride, ≥97.0% (NT)
InChI key
NHGXDBSUJJNIRV-UHFFFAOYSA-M
InChI
1S/C16H36N.ClH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
SMILES string
[Cl-].CCCC[N+](CCCC)(CCCC)CCCC
assay
≥97.0% (NT)
form
crystals
Quality Level
reaction suitability
core: ammonium
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
impurities
≤1% water
solubility
H2O: 20 mg/mL, clear, colorless
greener alternative category
, Aligned
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General description
Tetrabutylammonium chloride is a quaternary ammonium salt that is commonly used as a phase transfer catalyst as well as a source of chloride ions in organic synthesis.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.
Application
Tetrabutylammonium chloride (TBACl) can be used as a phase transfer catalyst in the synthesis of:
TBACl can also be used with phosphorus pentoxide for greener deoxychlorination.
Process for Producing Halogenated Heteroaryl Compounds
- 2-Amino-4H-chromene derivatives by the condensation reaction of aldehydes, malononitrile, and α, or β-naphthol.
- Methyl esters by esterification reaction of carboxylic acids with dimethyl carbonate in the presence of K2CO3.
TBACl can also be used with phosphorus pentoxide for greener deoxychlorination.
Process for Producing Halogenated Heteroaryl Compounds
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
저장 등급
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Efficient and eco-friendly synthesis of 2-amino-4H-chromene derivatives using catalytic amount of tetrabutylammonium chloride (TBAC) in water and solvent-free conditions
Mehrabi H and Kamali N
Journal of the Iranian Chemical Society, 9, 599-605 (2012)
Nancy AlHaddad et al.
Organic & biomolecular chemistry, 17(31), 7330-7336 (2019-07-18)
The present study describes the synthesis of the first phenoxycalix[4]pyrrole-epichlorohydrin based polymer. The advantage of the latter resides in its fast-single step synthesis protocol, low cost, water insolubility and its unexpected anion extraction capacity. The study of this polymer by
I P E Macário et al.
Scientific reports, 9(1), 3932-3932 (2019-03-10)
The tailor-made character of deep eutectic solvents (DES) turns them very attractive to be used in several applications, including in health-related areas such as pharmaceutical, nutraceutical, and cosmetic industries. However, although DES has been touted as "green" solvents, several works
Tetrabutylammonium Chloride-Induced Cascade Radical Addition/Cyclization of O-Isocyanodiaryl Amines: A Novel Protocol for the Synthesis of 11-Trifluoromethylated Dibenzodiazepines
Yuan S, et al.
The Journal of Organic Chemistry, 87, 16542-16549 (2022)
Methyl esterification of carboxylic acids with dimethyl carbonate promoted by K2CO3/tetrabutylammonium chloride
Chau K, et al.
Green Chemistry Letters and Reviews, 6, 89-93 (2013)
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