86893
Tetrabutylammonium perchlorate
for electrochemical analysis, ≥99.0%
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크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
(CH3CH2CH2CH2)4N(ClO4)
CAS 번호:
Molecular Weight:
341.91
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
EC Number:
217-655-5
Beilstein/REAXYS Number:
3579274
MDL number:
Assay:
≥99.0% (T), ≥99.0%
Form:
powder
InChI key
KBLZDCFTQSIIOH-UHFFFAOYSA-M
InChI
1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
SMILES string
[O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
assay
≥99.0% (T), ≥99.0%
form
powder
mp
211-215 °C
solubility
acetonitrile: 0.1 g/mL, clear, colorless
Quality Level
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General description
Tetrabutylammonium perchlorate (TBAP) is a quaternary ammonium salt, mainly used as electrolyte.
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Application
TBAP has been used as solvent in preparing standard stock solutions, for HPLC analysis of Sudan azo-dyes food samples. It may be used as an electrophoretic buffer to rinse the capillary for the nonaqueous capillary electrophoresis (NACE) determination of atropine, anisodamine, and scopolamine in Flos daturae plant extract.
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
저장 등급
5.1B - Oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Simultaneous determination of atropine, anisodamine, and scopolamine in plant extract by nonaqueous capillary electrophoresis coupled with electrochemiluminescence and electrochemistry dual detection.
Yuan B
Journal of Chromatography A, 1217(1), 171-174 (2010)
Analysis of sudan I, sudan II, sudan III, and sudan IV in food by HPLC with electrochemical detection: Comparison of glassy carbon electrode with carbon nanotube-ionic liquid gel modified electrode.
Chailapakul O
Food Chemistry, 109(4), 876-882 (2008)
David Balcells et al.
Dalton transactions (Cambridge, England : 2003), (30)(30), 5989-6000 (2009-07-23)
Experimental studies have shown that the C-H oxidation of Ibuprofen and methylcyclohexane acetic acid can be carried out with high selectivities using [(terpy')Mn(OH(2))(mu-O)(2)Mn(OH(2))(terpy')](3+) as catalyst, where terpy' is a terpyridine ligand functionalized with a phenylene linker and a Kemp's triacid
Benjamin T Diroll et al.
Nature communications, 10(1), 4511-4511 (2019-10-06)
Colloidal quantum wells are two-dimensional materials grown with atomically-precise thickness that dictates their electronic structure. Although intersubband absorption in epitaxial quantum wells is well-known, analogous observations in non-epitaxial two-dimensional materials are sparse. Here we show that CdSe nanoplatelet quantum wells
Atanu Jana et al.
Dalton transactions (Cambridge, England : 2003), 44(1), 359-367 (2014-11-11)
A novel electron rich, tetrathiafulvalene fused zinc porphyrin, (TTF)4PZn, has been newly synthesized and characterized using spectral and electrochemical methods. In spite of the presence of eight t-butyl groups, (TTF)4PZn exhibited appreciable aggregation in solution. Scanning electron microscopic (SEM) imaging
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