Methyl 2-methylglycidate

Name: Methyl 2-methylglycidate
Brand: ALDRICH

99%

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About This Item

Fórmula empírica (notación de Hill):

C₅H₈O₃

Número CAS:

58653-97-7

Peso molecular:

116.12

NACRES:

NA.22

PubChem Substance ID:

24866542

UNSPSC Code:

12352100

MDL number:

MFCD00198125

Nombre del producto

Methyl 2-methylglycidate, 99%

InChI

1S/C5H8O3/c1-5(3-8-5)4(6)7-2/h3H2,1-2H3

SMILES string

COC(=O)C1(C)CO1

InChI key

OSYXXQUUGMLSGE-UHFFFAOYSA-N

assay

99%

refractive index

n20/D 1.418 (lit.)

bp

62-65 °C/32 mmHg (lit.)

density

1.097 g/mL at 25 °C (lit.)

functional group

ester
ether

Quality Level

100

Categorías relacionadas

Chemical Building Blocks

Chemistry & Biochemicals

Organic Building Blocks

Application

Methyl 2-methylglycidate may be used in the synthesis of:

2-methyl-2-hydroxy-1-propanol
2,3-dihydroxy-2-methyl propionic acid
methyl 2-hydroxy-3-((4-methoxyphenyl)sulfonyl)-2-methylpropanoate

General description

Methyl 2-methylglycidate (methyl 2-methyloxirane-2-carboxylate) is an ester derived epoxide. It is reported to be formed by the reaction of methyl pyruvate with diazomethane. It is formed as an intermediate in the synthesis of 1,2,4-oxadiazole derivatives.

pictograms

GHS02,GHS07

signalword

Warning

hcodes

H226,H315,H319,H335

pcodes

P210 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Clase de almacenamiento

3 - Flammable liquids

wgk

WGK 3

flash_point_f

129.2 °F - closed cup

flash_point_c

54 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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DABSO-Based, Three-Component, One-Pot Sulfone Synthesis.

Deeming AS, et al.

Organic Letters, 16(1), 150-153 (2013)

β-Keto phosphonic esters.

Arbuzov BA, et al.

Russian Chemical Bulletin, 12(4), 604-610 (1963)

1,2,4-Oxadiazoles: a new class of anti-prostate cancer agents.

Gopal L Khatik et al.

Bioorganic & medicinal chemistry letters, 22(5), 1912-1916 (2012-02-14)

Sulfide and sulfonyl derivatives of 1,2,4-oxadiazoles were synthesized and screened by MTT assay on the prostate cancer cells, DU-145. Six compounds were identified as potential anti-prostate cancer agents with IC(50) values ranging from 0.5 to 5.1μM. These compounds exhibited good

Biodegradation of the gasoline oxygenates methyl tert-butyl ether, ethyl tert-butyl ether, and tert-amyl methyl ether by propane-oxidizing bacteria.

R J Steffan et al.

Applied and environmental microbiology, 63(11), 4216-4222 (1997-11-15)

Several propane-oxidizing bacteria were tested for their ability to degrade gasoline oxygenates, including methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), and tert-amyl methyl ether (TAME). Both a laboratory strain and natural isolates were able to degrade each compound after

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