901591
18-Crown-6 solution
1.0 M in THF, liquid
Sinónimos:
1,4,7,10,13,16-Hexaoxacyclooctadecane
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Form:
liquid
Servicio técnico
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Permítanos ayudarleNombre del producto
18-Crown-6 solution, 1.0 M in THF
form
liquid
reaction suitability
core: crown ether
greener alternative product characteristics
Catalysis
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Greener Alternative Product
concentration
1.0 M in THF
density
0.944 g/mL
greener alternative category
SMILES string
O1CCOCCOCCOCCOCCOCC1
InChI
1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2
InChI key
XEZNGIUYQVAUSS-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
18-Crown-6 may be used to catalyze the N-alkylation of heterocyclic compounds and allylation of functionalized aldehydes.
Phase-transfer catalyst used in a chemoselective reduction of fused tetrazoles with NaBH4 and potassium hydroxide.
Additive for greener etherification using KF-alumina.
Additive for greener etherification using KF-alumina.
Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6
Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6
signalword
Danger
supp_hazards
Clase de almacenamiento
3 - Flammable liquids
flash_point_f
-2.0 °F
flash_point_c
-18.88 °C
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
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Phase-transfer alkylation of heterocycles in the presence of 18-crown-6 and potassium tert-butoxide.
Guida WC and Mathre DJ
The Journal of Organic Chemistry, 45(16), 3172-3176 (1980)
Preparation and purification of 18-crown-6 [1, 4, 7, 10, 13, 16-hexaoxacyclooctadecane].
Gokel GW, et al.
The Journal of Organic Chemistry, 39(16), 2445-2446 (1974)
Synthesis, 3275-3275 (2006)