763039
XantPhos Pd G3
95%, solid
别名:
[（4,5-双（二苯基膦）-9,9-二甲基呫吨）-2-（2 & # 8242;-氨基-1,1 & # 8242;-联苯）]甲磺酸钯（ⅱ）
选择尺寸
关于此项目
产品名称
XantPhos Pd G3, 95%
Quality Segment
product line
Buchwald precatalyst Generation 3
assay
95%
form
solid
feature
generation 3
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
mp
164-167 °C (decomposition)
functional group
phosphine
SMILES string
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC3(C)c4cccc(P(c5ccccc5)c6ccccc6)c4Oc7c(cccc37)P(c8ccccc8)c9ccccc9
InChI
1S/C39H32OP2.C12H10N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h3-28H,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key
AJVXPGQYAKUTGX-UHFFFAOYSA-M
General description
Application
- 帕默内酯（palmerolide）合成过程中的Negishi交叉偶联反应
- 三乙胺存在的情况下下杂芳基溴化物与一氧化碳（CO）的氨基羰基化反应。
- 聚糖基硫醇和糖苷配基卤化物之间通过形成C-S键进行偶联。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.
G3和G4 Buchwald预催化剂是一类最新的空气、湿度和热稳定型交叉偶联复合物，可用于键形成以实现其多功能性和高反应性。
All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.