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Merck

1.00264

Formic acid

greener alternative

98%-100%, for analysis EMSURE ACS,Reag. Ph Eur

別名:

Formic acid, Methanoic acid, Formylic acid

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この商品について

化学式:
HCOOH
CAS番号:
分子量:
46.03
UNSPSC Code:
12352106
EC Index Number:
200-579-1
NACRES:
NA.21
Beilstein/REAXYS Number:
1209246
MDL number:
Assay:
≥98% (alkalimetric)
Form:
liquid
Grade:
ACS reagent
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製品名

ギ酸, for analysis EMSURE® ACS,Reag. Ph Eur

grade

ACS reagent

Quality Segment

agency

reag. Ph. Eur.

vapor density

1.6 (vs air)

vapor pressure

44.8 mmHg ( 20 °C)

product line

EMSURE®

assay

≥98% (alkalimetric)

form

liquid

autoignition temp.

1004 °F

expl. lim.

12-38 % (v/v), 57 %

greener alternative product characteristics

Catalysis
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Greener Alternative Product

technique(s)

HPLC: suitable

impurities

≤500 ppm Acetic acid (CH3COOH)

evapn. residue

≤10 ppm

color

APHA: ≤10

refractive index

n20/D 1.370 (lit.)

pH

2.2 (20 °C, 10 g/L in H2O)

bp

100-101 °C (lit.), 101 °C/1013 hPa

mp

8.2-8.4 °C (lit.)

transition temp

flash point 49.5 °C

solubility

water: soluble

density

1.22 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤5 ppm, sulfate (SO42-): ≤5 ppm, sulfite (SO32-): ≤10 ppm

SMILES string

OC=O

cation traces

Ag: ≤0.020 ppm, Al: ≤0.050 ppm, Ba: ≤0.050 ppm, Be: ≤0.020 ppm, Bi: ≤0.10 ppm, Ca: ≤0.20 ppm, Cd: ≤0.050 ppm, Co: ≤0.020 ppm, Cr: ≤0.050 ppm, Cu: ≤0.020 ppm, Fe: ≤2.0 ppm, Ge: ≤0.050 ppm, K: ≤0.10 ppm, Li: ≤0.020 ppm, Mg: ≤0.50 ppm, Mn: ≤0.050 ppm, Mo: ≤0.020 ppm, NH4+: ≤10 ppm, Na: ≤0.50 ppm, Ni: ≤0.050 ppm, Pb: ≤0.020 ppm, Sr: ≤0.020 ppm, Ti: ≤0.10 ppm, Tl: ≤0.050 ppm, V: ≤0.050 ppm, Zn: ≤0.050 ppm, Zr: ≤0.10 ppm, heavy metals (as Pb): ≤10 ppm

greener alternative category

storage temp.

15-25°C

InChI

1S/CH2O2/c2-1-3/h1H,(H,2,3)

InChI key

BDAGIHXWWSANSR-UHFFFAOYSA-N

General description

分析用 エンシュア ACS,Reag. Ph Eur
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application


  • Modified QuEChERS method combined with ultra performance liquid chromatography-tandem mass spectrometry for detection of cyclopiazonic acid in feeds: This study demonstrates the use of 98-100% formic acid in a modified QuEChERS method, enhancing the efficiency of toxin detection in animal feeds, crucial for maintaining food safety and environmental health (Peng et al., 2024).

  • Adapting Fabric Phase Sorptive Extraction as an Innovative Multitool for Sample Transfer and Extraction in Pharmacokinetic Analysis Followed by LC-MS Determination of Levofloxacin in Plasma Samples: This study utilizes formic acid in developing advanced extraction methods for pharmacokinetic analysis, critical for drug development and therapeutic monitoring in pharmaceutical research (Ekin Dolaksız et al., 2024).

  • Stability Indicating Method Development and Validation of Glycyrrhizin Using RP-HPLC-DAD: Application to Glycyrrhiza glabra Extract: This research uses formic acid in chromatographic analyses to ensure the stability and quality of herbal medicine compounds, relevant in both pharmaceutical and biotechnological fields (Lyngdoh et al., 2024).

Analysis Note

Assay (alkalimetric)≥ 98.0 %Color≤ 10 HazenAcetic acid (CH₃COOH)≤ 500 ppmChloride (Cl)≤ 5 ppmSulfate (SO₄)≤ 5 ppmSulfite (SO₃)≤ 10 ppmHeavy metals (as Pb)≤ 10 ppmAg (Silver)≤ 0.020 ppmAl (Aluminium)≤ 0.050 ppmBa (Barium)≤ 0.050 ppmBe (Beryllium)≤ 0.020 ppmBi (Bismuth)≤ 0.10 ppmCa (Calcium)≤ 0.20 ppmCd (Cadmium)≤ 0.050 ppmCo (Cobalt)≤ 0.020 ppmCr (Chromium)≤ 0.050 ppmCu (Copper)≤ 0.020 ppmFe (Iron)≤ 2.0 ppmGe (Germanium)≤ 0.050 ppmK (Potassium)≤ 0.10 ppmLi (Lithium)≤ 0.020 ppmMg (Magnesium)≤ 0.50 ppmMn (Manganese)≤ 0.050 ppmMo (Molybdenum)≤ 0.020 ppmNH₄ (Ammonium)≤ 10 ppmNa (Sodium)≤ 0.50 ppmNi (Nickel)≤ 0.050 ppmPb (Lead)≤ 0.020 ppmSr (Strontium)≤ 0.020 ppmTi (Titanium)≤ 0.10 ppmTl (Thallium)≤ 0.050 ppmV (Vanadium)≤ 0.050 ppmZn (Zinc)≤ 0.050 ppmZr (Zirconium)≤ 0.10 ppmEvaporation residue≤ 10 ppmDilution testpasses testACS, Ph Eur-Reagent
Expiry date : see product label

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany


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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

supp_hazards

保管分類

3 - Flammable liquids

wgk

WGK 1

flash_point_f

121.1 °F - closed cup

flash_point_c

49.5 °C - closed cup


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

劇物

pdsc

第4類:引火性液体 + 第二石油類 + 危険等級III + 水溶性液体

fsl

名称等を表示すべき危険物及び有害物

ishl_indicated

名称等を通知すべき危険物及び有害物

ishl_notified

1002640000: + 1002640510: + 1002649026: + 1002642500: + 1002642508: + 1002642511: + 1002649999: + 1002649950: + 1002640100: + 1002642510: + 1002641000: + 1002649200: + 1002641011:

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