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AdBrettPhos Pd G6 Br

powder or crystals

greener alternative

より環境に優しい遞択肢

別名:

AdBrettPhos OAC precatalyst Br

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実隓匏ヒル衚蚘法:
C50H65BrF3O2PPd
CAS番号:
3031171-47-5
分子量:
972.34
UNSPSC Code:
12352100
NACRES:
NA.22
eCl@ss:
32035490
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補品名

AdBrettPhos Pd G6 Br,

Quality Segment

product line

Buchwald precatalyst Generation 6

form

powder or crystals

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
core: palladium
reaction type: Cross Couplings

sustainability

Sustainability features

SMILES string

FC(F)(F)C1=CC=[C-](C=C1)[Pd+2]([Br-])[P](C=2C(OC)=CC=C(OC)C2C=3C(=CC(=CC3C(C)C)C(C)C)C(C)C)(C45CC6CC(CC(C6)C4)C5)C78CC9CC(CC(C9)C7)C8

InChI

InChI=1S/C43H61O2P.C7H4F3.BrH.Pd/c1-25(2)34-17-35(26(3)4)39(36(18-34)27(5)6)40-37(44-7)9-10-38(45-8)41(40)46(42-19-28-11-29(20-42)13-30(12-28)21-42)43-22-31-14-32(23-43)16-33(15-31)24-43;8-7(9,10)6-4-2-1-3-5-6;;/h9-10,17-18,25-33H,11-16,19-24H2,1-8H3;2-5H;1H;/q;-1;;+2/p-1

InChI key

XSUZJQPIWXBVTH-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This precatalyst excels in Suzuki-Miyaura reactions with sterically hindered and heteroaryl substrates. Its bulky AdBrettPhos ligand enables efficient coupling even at low loadings under mild conditions. Click here for more information.

Application

AdBrettPhos Pd G6 Br is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

保管分類

11 - Combustible Solids

WGK

WGK 3

匕火点 (F)

Not applicable

匕火点°C

Not applicable

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