製品名
水酸化カリウム 溶液, c(KOH) = 0.5 mol/l (0.5 N), Titripur®, reag. USP
agency
reag. USP
Quality Segment
product line
Titripur®
form
liquid
quality
Analyzed in our ISO 17025 accredited QC lab
reaction suitability
reaction type: Acid-base reactions
concentration
0.5 M
technique(s)
titration: suitable
pH
>13.5 (20 °C in H2O)
density
1.02 g/cm3 at 20 °C
storage temp.
15-25°C
SMILES string
[K+].[O-][H]
InChI
1S/K.H2O/h;1H2/q+1;/p-1
InChI key
KWYUFKZDYYNOTN-UHFFFAOYSA-M
Application
- Voltammetric Determination: Potassium hydroxide solution in ethanol is used in voltammetric determination of antioxidants in various matrices. A recent study demonstrated its application in the voltammetric determination of the antioxidant 2,6-di-tert-butyl-p-cresol (T501) in transformer oil using a graphite electrode. This method enhances the sensitivity and accuracy of antioxidant detection, crucial for ensuring the stability and performance of oils and other industrial fluids (Zhou et al., Analytical Letters, 2021).
- Oxidative Degradation Studies: The reagent is employed in oxidative degradation studies of organic compounds. For instance, it has been used in the oxidative degradation of piperazine in potassium hydroxide solution for CO2 absorption processes. This application is essential for developing efficient CO2 capture and storage technologies, contributing to environmental sustainability and climate change mitigation (Ochedi et al., SSRN Electronic Journal, 2022).
- CO2 Absorption and Modeling: Potassium hydroxide solution in ethanol is used in experimental and modeling studies of CO2 absorption processes. Recent research has focused on the absorption of CO2 into potassium hydroxide aqueous solution, providing valuable data for optimizing industrial CO2 capture methods. This application is crucial for enhancing the efficiency and effectiveness of carbon capture technologies (Rastegar and Ghaemi, Heat and Mass Transfer, 2022).
Features and Benefits
Digital Titration
ChemiSphere™ App for Digital Data Transfer to OMNIS Titration Instruments from Metrohm
Discover the ChemiSphere™ App for secure, rapid data transfer to OMNIS titrators, enhancing efficiency in the titration workflow with Titripur® and Aquastar® reagents. ChemiSphere App for Digital Reagent Data Transfer
SmartChemicals for Digital Data Transfer to Mettler Toledo Titration Instruments
Explore digital data transfer with our SmartChemicals for Mettler Toledo titrators—fast, easy, and safe, accelerating the titration process with Titripur®, Aquastar® reagents, and Certipur® and Aquastar® standards. Supelco® SmartChemicals for Titration
ChemiSphere™ App for Digital Data Transfer to OMNIS Titration Instruments from Metrohm
Discover the ChemiSphere™ App for secure, rapid data transfer to OMNIS titrators, enhancing efficiency in the titration workflow with Titripur® and Aquastar® reagents. ChemiSphere App for Digital Reagent Data Transfer
SmartChemicals for Digital Data Transfer to Mettler Toledo Titration Instruments
Explore digital data transfer with our SmartChemicals for Mettler Toledo titrators—fast, easy, and safe, accelerating the titration process with Titripur®, Aquastar® reagents, and Certipur® and Aquastar® standards. Supelco® SmartChemicals for Titration
Accreditation:
This volumetric solution is analyzed by our calibration laboratory D-K-15185-01-00 which is accredited according to DIN EN ISO/IEC 17025 for analysis of amount-of-substance concentrations in volumetric solutions by DAkkS (Deutsche Akkreditierungsstelle - German National Accreditation Body). The accreditation certificate can be found at www.sigmaaldrich.com/ISO17025.
This volumetric solution is analyzed by our calibration laboratory D-K-15185-01-00 which is accredited according to DIN EN ISO/IEC 17025 for analysis of amount-of-substance concentrations in volumetric solutions by DAkkS (Deutsche Akkreditierungsstelle - German National Accreditation Body). The accreditation certificate can be found at www.sigmaaldrich.com/ISO17025.
Analysis Note
Form liquid
Amount-of-substance concentration 0.4975 - 0.5025 mol/L
Measurement uncertainty ± 0.0015 mol/L
Traceability NIST SRM
The concentration is determined by volumetric titration and refers to 20°C.
The amount-of-substance concentration of this volumetric solution is traceable to a primary standard reference material (SRM) from the National Institute of Standards and Technology, Gaithersburg, USA (NIST SRM 84 potassium hydrogen phthalate) by means of volumetric standard potassium hydrogen phthalate (article number 1.02400), certified reference material according to ISO 17034, analyzed by our accredited calibration laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025. The uncertainty is expressed as expanded measurement uncertainty with a coverage factor k=2 covering a confidence level of 95%.
Note: The titer is a correction factor to correct for variations of the volumetric solution, the titration equipment, the temperature and other laboratory conditions. For correct titration results it is recommended to determine a titer with the laboratory specific equipment and under laboratory specific conditions directly after opening a new bottle and at regular time intervals.
Amount-of-substance concentration 0.4975 - 0.5025 mol/L
Measurement uncertainty ± 0.0015 mol/L
Traceability NIST SRM
The concentration is determined by volumetric titration and refers to 20°C.
The amount-of-substance concentration of this volumetric solution is traceable to a primary standard reference material (SRM) from the National Institute of Standards and Technology, Gaithersburg, USA (NIST SRM 84 potassium hydrogen phthalate) by means of volumetric standard potassium hydrogen phthalate (article number 1.02400), certified reference material according to ISO 17034, analyzed by our accredited calibration laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025. The uncertainty is expressed as expanded measurement uncertainty with a coverage factor k=2 covering a confidence level of 95%.
Note: The titer is a correction factor to correct for variations of the volumetric solution, the titration equipment, the temperature and other laboratory conditions. For correct titration results it is recommended to determine a titer with the laboratory specific equipment and under laboratory specific conditions directly after opening a new bottle and at regular time intervals.
Legal Information
AQUASTAR is a registered trademark of Merck KGaA, Darmstadt, Germany
CERTIPUR is a registered trademark of Merck KGaA, Darmstadt, Germany
ChemiSphere is a trademark of Merch KGaA, Darmstadt, Germany
Supelco is a registered trademark of Merck KGaA, Darmstadt, Germany
Titripur is a registered trademark of Merck KGaA, Darmstadt, Germany
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注意喚起語
Danger
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
一体何が起きているの?
nwg
引火点 (F)
Not applicable
引火点(°C)
Not applicable
ハザードコード
保管分類
8B - Non-combustible corrosive hazardous materials
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
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