8.02540
Cobalt(II) chloride anhydrous
for synthesis
別名:
Cobalt(II) chloride anhydrous, Cobalt dichloride
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この商品について
化学式:
CoCl2
CAS番号:
分子量:
129.84
UNSPSC Code:
12352302
EC Index Number:
231-589-4
NACRES:
NA.22
MDL number:
grade
anhydrous
Quality Segment
form
powder
potency
418 mg/kg LD50, oral (Rat)
mp
735 °C
solubility
soluble 585.9 g/L
density
3.36 g/cm3 at 25 °C
storage temp.
2-30°C
SMILES string
[Co+2].[Cl-].[Cl-]
InChI
1S/2ClH.Co/h2*1H;/q;;+2/p-2
InChI key
GVPFVAHMJGGAJG-UHFFFAOYSA-L
Application
Cobalt(II) chloride anhydrous (CoCl2) can be used as a catalyst in organic synthesis for the transformation of the various functional groups. For example, synthesis of esters via cleavage of ethers by acyl chlorides; acylation of alcohols and amines by anhydrides; and regioselective cleavage of oxiranes. It is also used to synthesize mixed acetals by the addition reaction between alcohols and vinyl ethers.
CoCl2 can be used as a catalyst:
CoCl2 can also be used as:
CoCl2 can be used as a catalyst:
- For the dealkylation of tertiary amines.
- In the synthesis of thioketones and thioaldehydes via thionation of carbonyl compounds in the presence of bis(trimethylsilyl) sulfide.
- In the oxidation of aromatic and aliphatic aldehydes to carboxylic acids in the presence of molecular oxygen and acetic anhydride.
- In the stereoselective opening of epoxides with N-substituted anilines.
CoCl2 can also be used as:
- A precursor to synthesize magnetic cobalt nanorods via decomposition of the cobalt coordination complex.
- A catalyst to prepare acid anhydrides by the reaction of acid chlorides with carboxylic acids.
- A reagent in the carbon-carbon bond-forming reactions involving active methylene compounds.
Analysis Note
Assay (argentometric): ≥ 98.0 %
Water (K. F.): ≤ 2.0 %
Water (K. F.): ≤ 2.0 %
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
保管分類
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
Substances Subject to be Indicated Names
ishl_indicated
Substances Subject to be Notified Names
ishl_notified
Class I Designated Chemical Substances
prtr