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36685

2-アミノピリジン

Name: 2-アミノピリジン
Brand: SIAL

PESTANAL^®, analytical standard

別名:

2-AP, 2-ピリジルアミン, 2-ピリジンアミン

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この商品について

実験式（ヒル表記法）:

C₅H₆N₂

CAS番号:

504-29-0

分子量:

94.11

UNSPSC Code:

41116107

NACRES:

NA.24

PubChem Substance ID:

329755451

EC Number:

207-988-4

Beilstein/REAXYS Number:

105785

MDL number:

MFCD00006312

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grade

analytical standard

Quality Level

100

product line

PESTANAL^®

assay

98-100% (GC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

bp

204-210 °C (lit.)

mp

54-58 °C (lit.)

application(s)

agriculture
environmental

format

neat

SMILES string

Nc1ccccn1

InChI

1S/C5H6N2/c6-5-3-1-2-4-7-5/h1-4H,(H2,6,7)

InChI key

ICSNLGPSRYBMBD-UHFFFAOYSA-N

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General description

2-Aminopyridine can be called as structural motifs, which can be encountered in a variety of useful compounds, that includes fluorescent organic materials and therapeutics. It can undergo condensation with an aromatic aldehyde to give the corresponding schiff′s base.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

GHS06,GHS05

signalword

Danger

hcodes

H301 + H311,H314,H412

pcodes

P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A

保管分類

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

197.6 °F - closed cup

flash_point_c

92 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

名称等を表示すべき危険物及び有害物

ishl_indicated

名称等を通知すべき危険物及び有害物

ishl_notified

36685-1G:4.548173381435E12

jan

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Pd?PEPPSI?IPentCl: A Useful Catalyst for the Coupling of 2?Aminopyridine Derivatives

Khadra A, et al.

Chemistry?A European Journal , 23, 3206-3212 (2017)

A novel approach towards design, synthesis and evaluation of some Schiff base analogues of 2-aminopyridine and 2-aminobezothiazole against hepatocellular carcinoma

Chacko S and Samanta S

Biomedicine and Pharmacotherapy, 89, 162-176 (2017)

Vibrational quenching of excitonic splittings in H-bonded molecular dimers: the electronic Davydov splittings cannot match experiment.

Philipp Ottiger et al.

The Journal of chemical physics, 136(17), 174308-174308 (2012-05-16)

The S(1)/S(2) state exciton splittings of symmetric doubly hydrogen-bonded gas-phase dimers provide spectroscopic benchmarks for the excited-state electronic couplings between UV chromophores. These have important implications for electronic energy transfer in multichromophoric systems ranging from photosynthetic light-harvesting antennae to photosynthetic

A direct intramolecular C-H amination reaction cocatalyzed by copper(II) and iron(III) as part of an efficient route for the synthesis of pyrido[1,2-a]benzimidazoles from N-aryl-2-aminopyridines.

Honggen Wang et al.

Journal of the American Chemical Society, 132(38), 13217-13219 (2010-09-09)

A novel and efficient synthesis of pyrido[1,2-a]benzimidazoles through direct intramolecular aromatic C-H amination of N-aryl-2-aminopyridines has been developed. The reaction, cocatalyzed by Cu(OAc)(2) and Fe(NO(3))(3)·9H(2)O, is carried out in DMF under a dioxygen atmosphere. Diversified pyrido[1,2-a]benzimidazoles containing various substitution patterns

Triple-helical recognition of RNA using 2-aminopyridine-modified PNA at physiologically relevant conditions.

Thomas Zengeya et al.

Angewandte Chemie (International ed. in English), 51(50), 12593-12596 (2012-11-06)

Peptide nucleic acids containing thymidine and 2-aminopyridine (M) nucleobases form stable and sequence-selective triple helices with double-stranded RNA at physiologically relevant conditions. The M-modified PNA showed unique RNA selectivity by having two orders of magnitude higher affinity for the double-stranded