Millipore Sigma Vibrant Logo

806373 Sodium borohydride

Sodium borohydride fine granular for synthesis. CAS No. 16940-66-2, EC Number 241-004-4.

Sodium borohydride MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Sodium tetrahydridoborate

CAS #: 16940-66-2 EC Number: 241-004-4 Molar Mass: 37.83 g/mol Chemical Formula: NaBH₄ Hill Formula: H₄BNa
View Products on Sigmaaldrich.com
806373
View Pricing & Availability

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
16940-66-2241-004-4H₄BNaNaBH₄37.83 g/mol

Pricing & Availability

Catalogue Number AvailabilityPackaging Qty/Pack Price Quantity
8063730010
Retrieving availability...
—
Limited Availability Limited Availability
In Stock 
Discontinued
Limited Quantities Available
Availability to be confirmed
    Remaining : Will advise
      Remaining : Will advise
      Will advise
      Contact Customer Service
      Contact Customer Service

      		 Glass bottle 10 g
      Retrieving price...
      Price could not be retrieved
      Minimum Quantity is a multiple of
      Maximum Quantity is
      Upon Order Completion More Information
      You Saved ()
       
      —
      Request Pricing
      		 —
      8063730025
      Retrieving availability...
      —
      Limited Availability Limited Availability
      In Stock 
      Discontinued
      Limited Quantities Available
      Availability to be confirmed
        Remaining : Will advise
          Remaining : Will advise
          Will advise
          Contact Customer Service
          Contact Customer Service

          		 25 g
          Retrieving price...
          Price could not be retrieved
          Minimum Quantity is a multiple of
          Maximum Quantity is
          Upon Order Completion More Information
          You Saved ()
           
          —
          Request Pricing
          		 —
          8063730100
          Retrieving availability...
          —
          Limited Availability Limited Availability
          In Stock 
          Discontinued
          Limited Quantities Available
          Availability to be confirmed
            Remaining : Will advise
              Remaining : Will advise
              Will advise
              Contact Customer Service
              Contact Customer Service

              		 100 g
              Retrieving price...
              Price could not be retrieved
              Minimum Quantity is a multiple of
              Maximum Quantity is
              Upon Order Completion More Information
              You Saved ()
               
              —
              Request Pricing
              		 —
              8063730500
              Retrieving availability...
              —
              Limited Availability Limited Availability
              In Stock 
              Discontinued
              Limited Quantities Available
              Availability to be confirmed
                Remaining : Will advise
                  Remaining : Will advise
                  Will advise
                  Contact Customer Service
                  Contact Customer Service

                  		 Glass bottle 500 g
                  Retrieving price...
                  Price could not be retrieved
                  Minimum Quantity is a multiple of
                  Maximum Quantity is
                  Upon Order Completion More Information
                  You Saved ()
                   
                  —
                  Request Pricing
                  		 —
                  Description
                  Catalogue Number806373
                  SynonymsSodium tetrahydridoborate
                  References
                  Product Information
                  CAS number16940-66-2
                  EC number241-004-4
                  Hill FormulaH₄BNa
                  Chemical formulaNaBH₄
                  Molar Mass37.83 g/mol
                  HS Code2850 00 90
                  Quality LevelMQ200
                  Applications
                  ApplicationSodium borohydride fine granular for synthesis. CAS No. 16940-66-2, EC Number 241-004-4.
                  Biological Information
                  Physicochemical Information
                  Boiling point500 °C (decomposition)
                  Density1.07 g/cm3 (20 °C)
                  Explosion limit3.02 %(V)
                  Flash point69 °C not applicable
                  Ignition temperature220 °C
                  Melting Point>360 °C (slow decomposition)
                  pH value11 (10 g/l, H₂O, 20 °C)
                  Vapor pressure<1 hPa (25 °C)
                  Bulk density350 - 500 kg/m3
                  Dimensions
                  Materials Information
                  Toxicological Information
                  LD 50 oralLD50 Rat 160 mg/kg
                  LD 50 dermalLD50 Rabbit 230 mg/kg
                  Safety Information according to GHS
                  Hazard Pictogram(s) Hazard Pictogram(s)
                  Hazard Pictogram(s)
                  Hazard Pictogram(s)
                  Hazard Pictogram(s)
                  Hazard Statement(s)H260: In contact with water releases flammable gases which may ignite spontaneously.
                  H301: Toxic if swallowed.
                  H314: Causes severe skin burns and eye damage.
                  H360FD: May damage fertility. May damage the unborn child.
                  EUH014: Reacts violently with water.
                  Precautionary Statement(s)P231 + P232: Handle and store contents under inert gas. Protect from moisture.
                  P260: Do not breathe dust.
                  P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
                  P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
                  P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
                  P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
                  P402 + P404: Store in a dry place. Store in a closed container.
                  Signal WordDanger
                  RTECSED3325000
                  Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
                  WGKWGK 2 obviously hazardous to water
                  Disposal26
                  Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
                  Safety Information
                  Categories of dangerhighly flammable, toxic, corrosive
                  Product Usage Statements
                  Storage and Shipping Information
                  StorageStore below +30°C.
                  Packaging Information
                  Transport Information
                  Declaration (railroad and road) ADR, RIDUN 1426 , 4.3, I
                  Declaration (transport by air) IATA-DGRUN 1426 , 4.3, I
                  Declaration (transport by sea) IMDG-CodeUN 1426 , 4.3, I
                  Supplemental Information
                  Specifications
                  Color according to Munsell color systemnot more intensely colored than reference standard NE12
                  Assay (hypochlorite)≥ 98.0 %
                  Identity (ICP-OES)passes test
                  Global Trade Item Number
                  Catalogue Number GTIN
                  8063730010 04027269275990
                  8063730025 04022536776262
                  8063730100 04022536390673
                  8063730500 04022536564265

                  Documentation

                  Sodium borohydride SDS

                  Title

                  Safety Data Sheet (SDS) 

                  Sodium borohydride Certificates of Analysis

                  Product Number PackagingLot Number
                  8063730010 Glass bottle
                  8063730025
                  8063730100
                  8063730500 Glass bottle

                  Related Products & Applications

                  Categories

                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reagents for Organometallic Synthesis
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Hydrides and Amides
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Boric Compounds
                  Reagents, Chemicals and Labware > Organic Synthesis > XXS Products in Small Quantities
                  Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reduction Reagents
                  Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Boric Compounds
                  Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Boric Compounds
                  Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Organometallic Synthesis
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents