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Merck

103543

4-Nitroanisole

97%

Sinónimos:

1-Methoxy-4-nitrobenzene

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Fórmula lineal:
O2NC6H4OCH3
Número CAS:
100-17-4
Peso molecular:
153.14
NACRES:
NA.22
PubChem Substance ID:
24846610
eCl@ss:
39032065
UNSPSC Code:
12352100
EC Number:
202-825-3
MDL number:
MFCD00007327
Beilstein/REAXYS Number:
1865361
Assay:
97%
Form:
solid

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InChI key

BNUHAJGCKIQFGE-UHFFFAOYSA-N

InChI

1S/C7H7NO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3

SMILES string

COc1ccc(cc1)[N+]([O-])=O

assay

97%

form

solid

density

1.233 g/mL at 25 °C (lit.)

functional group

nitro

Quality Level

100

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Categorías relacionadas

General description

4-Nitroanisole undergoes photochemical nucleophilic aromatic substitution by hydroxide ion to form 4-methoxyphenol and 4-nitrophenol.

Application

4-Nitroanisole was used as probe to determine Π* of Kamlet-Taft solvent parameters and high pressure and supercritical water in the temperature range of 16-420 °C. 4-Nitroanisole was used as carbon and energy supplement for the isolation of Rhodococcus strains.

Biochem/physiol Actions

4-Nitroanisole is O-demethylated to 4-nitrophenol by human liver microsomes.

pictograms

Health hazard
GHS08

signalword

Warning

hcodes

H351,H412

Hazard Classifications

Aquatic Chronic 3 - Carc. 2

Clase de almacenamiento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

266.0 °F - closed cup

flash_point_c

130 °C - closed cup

ppe

Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
STBF7314V
STBF4722V
STBD0772V
STBC8738V
STBC7426V

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D J Sequeira et al.
Biochimica et biophysica acta, 1207(2), 179-186 (1994-08-17)
The goal of this study was to examine the effect of duration of ethylbenzene exposure on cytochrome P-450-dependent activities. Male rats were treated with ethylbenzene by intraperitoneal injection for either 1 or 3 days, and microsomal preparations were examined for
A Schäfer et al.
Biodegradation, 7(3), 249-255 (1996-06-01)
Two Rhodococcus strains, R. opacus strain AS2 and R. erythropolis strain AS3, that were able to use 4-nitroanisole as the sole source of carbon and energy, were isolated from environmental samples. The first step of the degradation involved the O-demethylation
Andrea Ciani et al.
Chemosphere, 61(10), 1410-1418 (2005-07-12)
The kinetics of direct photochemical transformations of organic compounds in light absorbing and scattering media has been sparsely investigated. This is mostly due to the experimental difficulties to assess the major parameters: light intensity in porous media, the reaction quantum
Andrea Ciani et al.
Environmental science & technology, 39(17), 6712-6720 (2005-09-30)
Photodegradation is a key process in governing the residence time and fate of many agrochemicals in top soils. However, the basic knowledge of the photolytic transformation reactions of organic chemicals on soil surfaces is still very poor, particularly regarding the
Kimitaka Minami et al.
Physical chemistry chemical physics : PCCP, 8(19), 2257-2264 (2006-05-12)
Kamlet-Taft solvent parameters, pi*, of high pressure and supercritical water were determined from 16-420 degrees C based on solvatochromic measurements of 4-nitroanisole. For the measurements, an optical cell that could be used at high temperatures and pressures was developed with
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